Publications

Table of Contents

I. Peer-reviewed original Contributions
2024 2018 - 2017
2023 2016 - 2011
2022 2010 - 2006 II. Review Articles (Peer Reviewed)
2021 2005 - 2001 III. Other Contributions / Non Refereed
2020 2000 - 1996 IV. Book Chapters / Books
2019 1995 - 1991 V. Patents filed

 

2024

Reviews
 

Original Contributions

386. "Supersoft Polymer Melts in Binary Blends of Bottlebrush cis-1,4-Polyfarnesene and cis-1,4-Polyisoprene"
I. Tzourtzouklis, M. Meier-Merziger, H. Frey, G. Floudas. Macromol. Rapid Commun. 2024, 2400551.
DOI: 10.1002/marc.202400551
385. "Polymerization of Epoxides at a Static Oil-Alkaline Water Interface"
R. Verbeke, G. M. Linden, P. Dreier, C. Kampf, H. Frey. Macromol. Rapid Commun. 2024, 2400423.
DOI: 10.1002/marc.202400423
384. "Spotlight on Methyl tert-Butyl Ether─Underrated or Overlooked? Unveiling Its Role for Living Anionic Polymerization"
M. Meier-Merziger, D. A. H. Fuchs, H. Frey, A. H. E. Müller. Macromolecules 2024, XXXXX .
DOI: 10.1021/acs.macromol.4c01262
383. "Anionic polymerization of phenyl-substituted isoprene derivatives: polymerization behaviour and cyclization-enabled fluorescence"
M. Rauschenbach, L. Stein, G. M. Linden, R. Barent, K. Heinze, H. Frey. Polym. Chem. 2024, XXXXX .
DOI: 10.1039/D4PY00601A
382. "Effect of tetrahydrofuran on the anionic copolymerization of 4-trimethylsilylstyrene with isoprene"
D. A. H. Fuchs, S. P. Wadgaonkar, A. H. E. Müller, H. Frey. Polym. Adv. Technol. 2024, 35, 6, e6478 .
DOI: 10.1002/pat.6478
381. "One-step Synthesis of Fully Biobased Two-Sided Tapered ABA-type Thermoplastic Elastomers"
M. Meier-Merziger, N. Fotaras, I. Tzourtzouklis, C. Allouch, M. Wagner, A. H. E. Müller, G. Floudas, H. Frey. ACS Sustainable Chem. Eng. 2024, XXX, XXXX .
DOI: 10.1021/acssuschemeng.4c02530
380. "CO2-Based Polycarbonates with Low Glass Transition Temperatures Sourced from Long-Chain Terpenes"
P. Holzmüller, C. Gardiner, J. Preis, H. Frey. Macromolecules 2024, 57, 11, 5358-5367 .
DOI: 10.1021/acs.macromol.4c00349
379. "Anionic polymerization of ferulic acid-derived, substituted styrene monomers"
C. Hahn, S. Becker, A. H. E. Müller, H. Frey. J. Eur. Pol. J. 2024, 211, 113004 .
DOI: 10.1016/j.eurpolymj.2024.113004

 

2023

Reviews
 

Original Contributions

378. "Nopadiene:A Pinene-Derived Cyclic Diene as a Styrene Substitute for Fully Biobased Thermoplastic Elastomers"
C. Hahn, I. Göttker-Schnetmann, I. Tzourtzouklis, M. Wagner, A. H. E. Müller, G. Floudas, S. Mecking, H. Frey. J. Am. Chem. Soc. 2023, 145, 26688-26698 .
DOI: 10.1021/jacs.3c08130
377. "Biobased Thermoplastic Elastomers Derived from Citronellyl Glycidyl Ether, CO2, and Polylactide"
S. Schüttner, C. Gardiner, F. Petrov, N. Fotaras, J. Preis, G. Floudas, H. Frey. Macromolecules 2023, 56, 20, 8247-8259 .
DOI: 10.1021/acs.macromol.3c01329
376. "Anionic Ring-Opening Copolymerization of Farnesyl Glycidyl Ether: Fast Access to Terpenoid-Derived Amphiphilic Polyether Architectures"
S. Schüttner, M. Krappel, M. Koziol, L. Marquart, I. Schneider, T. Sottmann, H. Frey. Macromolecules 2023, 56, 17, 6928-6940 .
DOI: 10.1021/acs.macromol.3c00999
375. "Bifunctional Carbanionic Synthesis of Fully Bio-Based Triblock Structures Derived from β‑Farnesene and II‑Dilactide: Thermoplastic Elastomers"
M. Meier-Merziger, J. Imschweiler, F. Hartmann, B.‑J. Niebuur, T. Kraus, M. Gallei, H. Frey. Angew. Chem., Int. Ed. 2023, 62, e202310519 .
DOI: 10.1002/ange.202310519
374. "Linear (IS)nI Multiblock Copolymers: Tailoring the Softness of Thermoplastic Elastomers by Flexible Polyisoprene End Blocks"
R. Barent, I. Perevyazko, N. Mikusheva, G. Floudas, H. Frey. Macromolecules, 2023, 56, 15, 5792-5802.
DOI: 10.1021/acs.macromol.3c00513
373. "Synthesis of phase-separated super-H-shaped triblock architectures: poly(L-lactide) grafted from telechelic polyisoprene"
M. Meier-Merziger, M. Fickenscher, F. Hartmann, B. Kuttich, T. Kraus, M. Gallei, H. Frey. Polym. Chem., 2023, 14 (23), 2820-2828.
DOI: 10.1039/d3py00230f
372. "Revealing the Monomer Gradient of Polyether Copolymers Prepared Using N-Heterocyclic Olefins: Metal-Free Anionic versus Zwitterionic Lewis Pair Polymerization"
E. Kersten, O. Linker, J. Blankenburg, M. Wagner, P. Walther, S. Naumann, H. Frey. Macromol. Chem. Phys., 2023, 2300097.
DOI: 10.1002/macp.202300097
371. "Merging Styrene and Diene Structures to a Cyclic Diene: Anionic Polymerization of 1‐Vinylcyclohexene (VCH)"
C. Hahn, M. Rauschenbach, H. Frey. Angew. Chem. Int. Ed., 2023, e202302907.
DOI: 10.1002/anie.202302907
370. "Tailoring thermoresponsiveness of biocompatible polyethers: copolymers of linear glycerol and ethyl glycidyl ether"
V. Müller, R. Matthes, M. Wagner, M. Bros, P. Dreier, H. Frey. Polymer Chemistry, 2023, 14, 2599-2609.
DOI: 10.1039/d3py00064h
369. "Anionic Polymerization of 4-Allyldimethylsilylstyrene: Versatile Polymer Scaffolds for Post-Polymerization Modification"
S. P. Wadgaonkar, M. Wagner, A. H. E. Müller, H. Frey. Macromolecules, 2023, 56, 3, 1053-1064.
DOI: 10.1021/acs.macromol.2c02202
368. "Anionic Polymerization of the Terpene-Based Diene β-Ocimene: Complex Mechanism Due to Stereoisomer Reactivities"
S. P. Wadgaonkar, M. Wagner, L. A. Baptista, R. Cortes-Huerto, H. Frey, A. H. E. Müller. Macromolecules, 2023, 56, 2, 664-677.
DOI: 10.1021/acs.macromol.2c02241

 

2022

Reviews

R40 "Polyethers Based on Short-Chain Alkyl Glycidyl Ethers: Thermoresponsive and Highly Biocompatible Materials"
R. Matthes, H. Frey. Biomacromolecules 2022, 23, 6, 2219–2235. DOI:10.1021/acs.biomac.2c00223
R39 "Rational Design of Tapered Multiblock Copolymers for Thermoplastic Elastomers"
M. Steube, T. Johann, R. D. Barent, A. H. E. Müller, H. Frey. Prog. Polym. Sci. 2022, 124, 101488. DOI: 10.1016/j.progpolymsci.2021.101488

 

Original Contributions

367. "Glycidyl Cinnamate: Copolymerization with Glycidyl Ethers, in-situ NMR Kinetics and Photocrosslinking"
K. Maciol, S. Schüttner, J. Blankenburg, T. Johann, H. Frey. Macromol. Chem. Phys., 2022, 2200366.
DOI: 10.1002/macp.202200366
366. "Molecular Dynamics and Viscoelastic Properties of the Biobased 1,4-Polymyrcene"
I. Tzourtzouklis, C. Hahn, H. Frey, G. Floudas. Macromolecules, 2022, 55, 19, 8766-8775.
DOI: 10.1021/acs.macromol.2c01507
365. "Geometric Requirements for Living Anionic Polymerization: Polymerization of rotationally constrained 1,3-Dienes"
R. Barent, M. Wagner, H. Frey. Polym. Chem., 2022, 13, 5478-5485.
DOI: 10.1039/D2PY00999D
364. "In Situ Kinetics Reveal the Influence of Solvents and Monomer Structure on the Anionic Ring-Opening Copolymerization of Epoxides"
P. Dreier, R. Matthes, R. Barent, S. Schüttner, A. H. E. Müller, H. Frey. Macromol. Chem. Phys., 2022, 2200209.
DOI: 10.1002/macp.202200209
363. "End group Functionality of 95 to 99%: Epoxide Functionalization of Polystyryl-Lithium Evaluated via Solvent Gradient Interaction Chromatography (SGIC)"
P. Dreier, J. Ahn, T. Chang, H. Frey. Macromol. Rapid Commun., 2022, 2200560.
DOI: 10.1002/marc.202200560
362. "Anionic Copolymerization of 4-Trimethylsilylstyrene: From Kinetics to Gradient and Block Copolymers"
S. P. Wadgaonkar, S. Schüttner, E. Berger-Nicoletti, A. H. E. Müller, H. Frey. Macromolecules, 2022, 55, 11, 4721–4732.
DOI: 10.1021/acs.macromol.2c00570
361. “MyrDOL, a Protected Dihydroxyfunctional Diene Monomer Derived from β‑Myrcene: Functional Polydienes from Renewable Resources via Anionic Polymerization”
C. Hahn, M. Wagner, A. H. E. Müller, H. Frey, Macromolecules 2022, 55, 10, 4046-4055.
DOI: 10.1021/acs.macromol.2c00367
360. “Dynamics of Poly(cyclohexene carbonate) as a Function of Molar Mass”
M. Spyridakou, C. Gardiner, G. Papamokos, H. Frey, G. Floudas. ACS Appl. Polym. Mater. 2022, 4, 5, 3833-3843.
DOI: 10.1021/acsapm.2c00299
359. “Ordering Kinetics of a Tapered Copolymer Based on Isoprene and Styrene”
E. Galanos, M. Steube, H.-J. Butt, H. Frey and G. Floudas. J. Chem. Phys. 2022, 156, 134904.
DOI: 10.1063/5.0086753
358. “Phase Diagram of Tapered Copolymers Based on Isoprene and Styrene”
E. Galanos, C. Wahlen, H.-J. Butt, H. Frey and G. Floudas. Macromol. Chem. Phys. 2022, 2200033.
DOI: 10.1002/macp.202200033
357. “Introduction of Trifluoromethanesulfonamide Groups in Poly(ethylene oxide): Ionic Conductivity of Single-Ion-Conducting Block Copolymer Electrolytes”
P. Dreier, A. Pipertzis, M. Spyridakou, R. Mathes, G. Floudas, and H. Frey, Macromolecules 2022, 55, 4, 1342-1353.
DOI: 10.1021/acs.macromol.1c02507

 

2021

Reviews

R38 "Anionic Polymerization of Terpene Monomers: New Options for Bio-Based Thermoplastic Elastomers"
C. Wahlen, H. Frey, Macromolecules 2021. DOI: 10.1021/acs.macromol.1c00770.

 

Original Contributions

356. “Unexpected Random Copolymerization of Propylene Oxide with Glycidyl Methyl Ether via Double Metal Cyanide-Catalysis: Introducing Polarity in Polypropylene oxide”
R. Matthes, C. Bapp, M. Wagner, S. Zarbakhsh, H. Frey, Macromolecules 2021, 54, 24, 11228-11237.
DOI: 10.1021/acs.macromol.1c02047
355. "The effect of THF and the chelating modifier DTHFP on the copolymerisation of β-myrcene and styrene: kinetics, microstructures, morphologies, and mechanical properties"
D. A. H. Fuchs, H. Hübner, T. Kraus, B.-J. Niebuur, M. Gallei, H. Frey, A. H. E. Müller, Polymer Chemistry 2021., 12, 4632-4642.
DOI: 10.1039/D1PY00791B.
354. "Introducing a 1,1-diphenylethylene analogue for vinylpyridine: anionic copolymerisation of 3-(1-phenylvinyl)pyridine (m-PyPE)"
M. Fickenscher, T. Reimers, H. Frey, Polymer Chemistry 2021. DOI: 10.1039/D1PY00302J.
353. "N-Oxide Polyethers as Kinetic Hydrate Inhibitors: Side Chain Ring Size Makes the Difference"
Q. Zhang, L. Limmer, H. Frey, M. A. Kelland, Energy Fuels 2021, 35, 5, 4067–4074 DOI: 10.1021/acs.energyfuels.0c04333.
352. "Building Bridges by Blending: Morphology and Mechanical Properties of Binary Tapered Diblock/Multiblock Copolymer Blends"
M. Steube, M. Plank, M. Gallei, H. Frey, G. Floudas, Macromol. Chem. Phys. 2021. DOI: 10.1002/macp.202000373.

 

2020

Reviews

R37 "Hyperbranched Polymer Architectures: From Flory´ s AB (f-1) Polycondensates to Controlled Structures"
T. Kaiser and H. Frey, Polymer 2020, 123113. DOI: 10.1016/j.polymer.2020.123113.
R36 "Hydroxamic Acid – An Underrated Moiety? Marrying Bioinorganic Chemistry and Polymer Science"
J. Keth, T. Johann and H. Frey, Biomacromolecules 2020. DOI: 10.1021/acs.biomac.0c00449.
R35 "Long-Chain Alkyl Epoxides and Glycidyl Ethers: An Underrated Class of Monomers"
P. Verkoyen and H. Frey, Macromol. Rapid Commun. 2020. DOI: 10.1002/marc.202000225.
R34 "Amino-functional polyethers: versatile, stimuli-responsive polymers"
P. Verkoyen and H. Frey, Polymer Chemistry 2020, 11, 3940-3950. DOI: 10.1039/D0PY00466A.

Original Contributions

351. "The Unique Versatility of the Double Metal Cyanide (DMC) Catalyst: Introducing Siloxane Segments to Polypropylene Oxide by Ring-Opening Copolymerization"
R. Mohr, M. Wagner, S. Zarbakhsh, and H. Frey, Macromol. Rapid Commun. 2020, DOI: 10.1002/marc.202000542.
350. "Tapered Multiblock Copolymers Based on Farnesene and Styrene: Impact of Biobased Polydiene Architectures on Material Properties"
C. Wahlen, J. Blankenburg, P. v. Tiedemann, J. Ewald, P. Sajkiewicz, A. H. E. Müller, G. Floudas, and H. Frey, Macromolecules 2020, DOI: 10.1021/acs.macromol.0c02118.
349. "“Hard” Sphere Behavior of “Soft”, Globular-like, Hyperbranched Polyglycerols – Extensive Molecular Hydrodynamic and Light Scattering Studies"
A. Lezov, A. Gubarev, T. Kaiser, W. Tobaschus, N. Tsvetkov, I. Nischang*, U. S. Schubert, H. Frey and I. Perevyazko, Macromolecules 2020, DOI: 10.1021/acs.macromol.0c01340.
348. "Temperature Variation Enables the Design of Biobased Block Copolymers via One‐Step Anionic Copolymerization"
J. Bareuther, M. Plank, B. Kuttich, T. Kraus, H. Frey and M. Gallei, Macromol. Rapid Commun. 2020, DOI: 10.1002/marc.202000513.
347. "Myrcenol-Based Monomer for Carbanionic Polymerization: Functional Copolymers with Myrcene and Bio-Based Graft Copolymers"
C. Wahlen, M. Rauschenbach, J. Blankenburg, E. Kersten, C. P. Ender and H. Frey, Macromolecules 2020, DOI: 10.1021/acs.macromol.0c01734.
346. "Stability of Alkyl Chain-Mediated Lipid Anchoring in Liposomal Membranes"
L. Gleue, J. Schupp, N. Zimmer, E. Becker, H. Frey, A. Tuettenberg, M. Helm, Cells 2020, 9, 2213, DOI: 10.3390/cells9102213.
345. "Efficiency Boosting of Surfactants with Poly(ethylene oxide)-Poly(alkyl glycidyl ether)s – A New Class of Amphiphilic Polymers"
K. Schneider, P. Verkoyen, M. Krappel, C. Gardiner, R. Schweins, H. Frey and T. Sottmann, Langmuir 2020, DOI: 10.1021/acs.langmuir.0c01491 .
344. "Tapered Multiblock Star Copolymers: Synthesis, Selective Hydrogenation, and Properties"
P. v. Tiedemann, J. Yan, R. D. Barent, R. J. Spontak, G. Floudas, H. Frey and R. A. Register, Macromolecules 2020, 53, 11, 4422–4434, DOI: 10.1021/acs.macromol.0c00645 .
343. " “Dumb” pH-Independent and Biocompatible Hydrogels Formed by Copolymers of Long-Chain Alkyl Glycidyl Ethers and Ethylene Oxide"
P. Verkoyen, P. Dreier, M. Bros, C. Hils, H. Schmalz, S. Seiffert and H. Frey, Biomacromolecules 2020, DOI: 10.1021/acs.biomac.0c00576 .
342. "Water-soluble hyperbranched polyglycerol photosensitizer for enhanced photodynamic therapy"
B. Xiang, Y. Xue, Z. Liu, J. Tian, H. Frey, Y. Gao, W. Zhang, Polym. Chem. 2020, 11, 3913-3921. DOI: 10.1039/D0PY00431F.
341. "Tetrahydrofuran: More than a “Randomizer” in the Living Anionic Copolymerization of Styrene and Isoprene: Kinetics, Microstructures, Morphologies, and Mechanical Properties"
M. Steube, T. Johann, H. Hübner, M. Koch, T. Dinh, M. Gallei, G. Floudas, H. Frey, and A. H. E. Müller, Macromolecules 2020. DOI: 10.1021/acs.macromol.0c01022.
340. "A Nonconventional Approach toward Multihydroxy Functional Polystyrenes Relying on a Simple Grignard Reagent"
P. v. Tiedemann, E. Kersten, J. Ewald, T. Linder, C. Fuchs, M. Wagner and H. Frey, Macromolecules 2020, 53, 9, 3370-3379. DOI: 10.1021/acs.macromol.0c00541.
339. "Amine N‑Oxide Kinetic Hydrate Inhibitor Polymers for High-SalinityApplications"
Q. Zhang, M. A. Kelland, H. Frey, J. Blankenburg, L. Limmer, Energy Fuels 2020, 34, 5, 6298-6305. DOI: 10.1021/acs.energyfuels.0c00838.
338. "Ester Functional Epoxide Monomers for Random and Gradient Poly(ethylene glycol) Polyelectrolytes with Multiple Carboxylic Acid Moieties"
O. Linker, J. Blankenburg, K Maciol, M. Bros and H. Frey, Macromolecules 2020, 53, 9, 3524-3534. DOI: 10.1021/acs.macromol.9b02320.
337. "Local and Subchain Relaxation of Polyisoprene in Multiblock Copolymers with a Tapered Interface"
C. Livitsanou, M. Steube, T. Johann, H. Frey and G. Floudas, Macromolecules 2020. DOI: 10.1021/acs.macromol.0c00445.
336. "Targeting of Immune Cells with Trimannosylated Liposomes"
K. Wagener, M. Bros, M. Krumb, J. Langhanki, S. Pektor, M. Worm, M. Schinnerer, E. Montermann, M. Miederer, H. Frey, T. Opatz, F. Rösch, Adv. Therap. 2020.
DOI: 10.1002/adtp.201900185.
335. "Synthesis and Solution Processing of Nylon‐5 Ferroelectric Thin Films: The Renaissance of Odd‐Nylons?"
P. von Tiedemann, S. Anwar, U. Kemmer‐Jonas, K. Asadi, H. Frey, Macromol. Chem. Phys. 2020, 221, 5, 1900468. DOI: 10.1002/macp.201900468.
334. "Acid‐cleavable Poly(ethylene Glycol) Hydrogels Displaying Protein Release at pH 5"
J. Ewald, J. Blankenburg, M. Worm, L. Besch, R. E. Unger, W. Tremel, H. Frey, H. Pohlit, Chem. Eur. J. 2020, 26, 13, 2947-2953. DOI: 10.1002/chem.201905310.
333. "Celebrating 100 years of "polymer science": Hermann Staudinger's 1920 manifesto"
T. Johann, H. Frey, Polym. Chem. 2020, 11, 8-14. DOI: 10.1039/C9PY90161B.
332. "pH-Responsive Protein Nanoparticles via Conjugation of Degradable PEG to the Surface of Cytochrome c"
E. Steiert, J. Ewald, A. Wagner, U. A. Hellmich, H. Frey, P. R. Wich, Polym. Chem. 2020, 11, 551-559. DOI: 10.1039/C9PY01162E
331. "Tapered Copolymers of Styrene and 4-Vinylbenzocyclobutene via Carbanionic Polymerization of Crosslinkable Polymer Films"
D. Leibig, M. Messerle, T. Johann, C. Moers, F. Kaveh, H.-J. Butt, D. Vollmer, A. H.E Müller,  H. Frey, J. Polym. Sci. Pol. Chem. 2020, 58, 11 181-192. DOI: 10.1002/pola.29515.
330. "Multi-Functional Fe(III)-Binding Polyethers from Hydroxamic Acid-Based Epoxide Monomers"
T. Johann, U. Kemmer-Jonas, R.D. Barent, H. Frey, Macromol. Rapid Commun. 2020, 41, 1, 1900282. DOI: 10.1002/marc.201900282.

 

2019

Original Contributions

329. "Kinetics of Anionic Living Copolymerization of Isoprene and Styrene Using in Situ NIR Spectroscopy: Temperature Effects on Monomer Sequence and Morphology"
M. Steube, T. Johann, M. Plank, S. Tjaberings, A. H. Gröschel, M. Gallei, H. Frey and A. H.E. Müller, Macromolecules 2019, 52 (23), 9299-9310. DOI: 10.1021/acs.macromol.9b01790.
328. “Solution-processed transparent ferroelectric nylon thin-films”
S. Anwar, D. Pinkal, W. Zajaczkowski, P. von Tiedemann, H. S. Dehsari, M. Kumar, T. Lenz, U. Kemmer-Jonas, W. Pisula, M. Wagner, R. Graf, H. Frey and K. Asadi, Sci. Adv. 2019, 5 (8), eaav3489. DOI: 10.1126/sciadv.aav3489
327. "Glycidyl tosylate: Polymerization of a "Non-Polymerizable” Monomer permits Universal Post-Functionalization of Polyethers"
P. Jung, A.D. Ziegler, J. Blankenburg, H. Frey, Angew. Chem. Int. Ed. 2019, 58, 37, 12883-12886. DOI: 10.1002/anie.201904203
326. "Multi-olefin containing polyethers and trizazolinediones: a powerful alliance"
T. Johann, H.A. Houck, T. Dinh, U. Kemmer-Jonas, F. Du Prez, H. Frey, Polym. Chem. 2019, 10, 4699-4708. DOI: 10.1039/C9PY00718K
325. "Functionalization of Liposomes with Hydrophilic Polymers Results in Macrophage Uptake Independent of the Protein Corona"
C. Weber, M. Voigt, J. Simon, AK. Danner, H. Frey, V. Mailänder, M. Helm, S. Morsbach, K. Landfester Biomacromolecules 2019, 20, 8, 2989-2999. DOI: 10.1021/acs.biomac.9b00539
324. "A general concept for the introduction of hydroxamic acids into polymers"
T. Johann, J. Keth, M. Bros, H. Frey, Chem. Sci. 2019,10, 7009-7022. DOI: 10.1039/c9sc02557j
323. "Effect of the Substituent Position on the Anionic Copolymerization of Styrene Derivatives: Experimental Results and Density Functional Theory Calculations"
T. Johann, D. Leibig, E. Grune, A. H. E. Müller, H. Frey, Macromolecules 2019, 52, 4545-4554. DOI: 10.1021/acs.macromol.9b00747
322. "Monomer-activated copolymerization of Ethylene Oxide and Epichlorohydrin:
In Situ Kinetics Evidences Tapered Block Copolymer Formation"
AK. Danner, D. Leibig, L.M. Vogt, H. Frey, Chin. J. Polym. Sci. 2019, 37, 912-918. DOI: 10.1007/s10118-019-2296-y
321. "Poly(propylene oxide-co-ethylene oxide) gradient is controlled by the polymerization method: determination of reactivity ratios by direct comparison of different copolymerization models"
J. Blankenburg, E. Kersten, K. Maciol, M. Wagner, S. Zarbakhsh, H. Frey, Polym. Chem. 2019, 10, 2863-2871. DOI: 10.1039/C9PY00500E.
320. "Phosphonylation Controls the Protein Corona of Multifunctional Polyglycerol Modified Nanocarriers"
AK. Danner, S. Schöttler., E. Alexandrino, S. Hammer, K. Landfester, V. Mailänder, S. Morsbach, H. Frey, FR. Wurm Macromol Biosci 2019, 19, 5, 1800468. DOI: 10.1002/mabi.201800468.
319. "Nonionic Aliphatic Polycarbonate Surfactants based on CO2, 1,2-Butylene Oxide and mPEG: Synthesis, Micellization and Solubilization."
L. Kunze, S.-Y Tseng., R. Schweins, T. Sottmann, H. Frey, Langmuir 2019, 35, 15, 5221-5231. DOI: 10.1021/acs.langmuir.8b04265
318. "Rapid One-Pot Synthesis of Tapered Star Copolymers via Ultra-fast Coupling of Polystyryllithium Chain Ends."
P. von Tiedemann, K. Maciol, J. Preis, P. Sajkiewicz, H. Frey, Polym Chem., 2019, 10, 1762-1768. DOI: 10.1039/C8PY01656A
317. "Aminal Protection of Epoxide Monomer Permits the Introduction of Multiple Secondary Amine Moieties at Poly(ethylene glycol)"
J. Blankenburg, H. Frey, Macromol. Rapid Commun. 2019, 40, 12, 1900057. DOI: 10.1002/marc.201900057.
316. "Oxidation-Responsive Polyether Block Copolymers Lead to Non-ionic Polymer Surfactants with Multiple Amine N-Oxides"
J. Blankenburg, M. Stark, H. Frey, Polym. Chem. 2019, 10, 1569-1574. DOI: 10.1039/C9PY00093C.
315. "Convenient access to α-amino-ω-hydroxyl heterobifunctional PEG and PPO via a sacrificial hexahydro-triazine star strategy"
J. Blankenburg, H. Frey, Macromol. Rapid Commun. 2019, 40, 9, 1900020. DOI: 10.1002/marc.201900020.
314. "Poly(ethylene glycol) with Multiple Aldehyde Functionalities Opens up a Rich and Versatile Post-Polymerization Chemistry"
J. Blankenburg, K. Maciol, C. Hahn, H. Frey, Macromolecules 2019, 52, 1785–1793. DOI: 10.1021/acs.macromol.8b02639.
313. "Tapered Multiblock Copolymers Based on Isoprene and 4-Methylstyrene: Influence of the Tapered Interface on the Self-Assembly and Thermomechanical Properties"
E. Galanos, E. Grune, C. Wahlen, A. H. E. Müller, M. Appold, M. Gallei, H. Frey, G. Floudas, Macromolecules 2019, 52, 1577–1588. DOI: 10.1021/acs.macromol.8b02669.
312. "Towards bio-based tapered block copolymers: the behaviour of myrcene in the statistical anionic copolymerisation"
E. Grune, J. Bareuther, J. Blankenburg, M. Appold, L. Shaw, A. H.E. Müller, G. Floudas, L. R. Hutchings, M. Gallei, H. Frey, Polym. Chem. 2019, 10, 1213. DOI: 10.1039/C8PY01711E.
311. "Copolymerization of Isoprene with p -Alkylstyrene Monomers: Disparate Reactivity Ratios and the Shape of the Gradient"
P. von Tiedemann, J. Blankenburg, K. Maciol, T. Johann, A. H.E. Müller, H. Frey, Macromolecules 2019, 44, 5327–5338. DOI: 10.1021/acs.macromol.8b02280.

2018

Reviews

R33. "Functional Polycarbonates from Carbon Dioxide and Tailored Epoxide Monomers: Degradable Materials and Their Application Potential"
M. Scharfenberg, J. Hilf, H. Frey, Adv. Funct. Mater. 2018, 28, 1704302. DOI: 10.1002/adfm.201704302.

Original Contributions

310. "Isoprene/Styrene Tapered Multiblock Copolymers with up to 10 Blocks: Synthesis, Phase Behaviour, Order and Mechanical Properties"
M. Steube, T. Johann, E. Galanos, M. Appold, C. Rüttiger, M. Mezger, M. Gallei, A. H.E. Müller, G. Floudas, H. Frey, Macromolecules 2018, 51, 10246–10258. DOI: 10.1021/acs.macromol.8b01961.
309. "Polymerization of long chain alkyl glycidyl ethers: a platform for micellar gels with tailor-made melting points",
P. Verkoyen, T. Johann, J. Blankenburg, C. Czysch, H. Frey, Polym. Chem. 2018, 43, 6641. DOI: 10.1039/C8PY01312H
308. "Crystalline CO2‐Based Aliphatic Polycarbonates with Long Alkyl Chains"
L. Kunze, J. Wolfs, P. Verkoyen, H. Frey, Macromol. Rapid Commun. 2018, e1800558. DOI: 10.1002/marc.201800558
307. "Iron Oxide Superparticles with Enhanced MRI Performance by Solution Phase Epitaxial Growth",
M. Kluenker, M.N. Nawaz, R. Dören, M. Deuker, P. Komforth, S. Plana-Ruiz, B. Barton, S. I. Shylin, V. Ksenofontov, M. Panthöfer, N. Wiesmann, J. Herzberger, A. Möller, H. Frey, J. Brieger, U. Kolb, W. Tremel, Chem. Mat., 2018, 30, 4277. DOI: 10.1021/acsami.8b02848.
306. "Particles of vaterite, a metastable CaCO3polymorph, exhibit high biocompatibility for human osteoblasts and endothelial cells and may serve as a biomaterial for rapid bone regeneration",
R. Schröder, L. Besch, H. Pohlit, M. Panthöfer, W. Roth, H. Frey, W. Tremel, R. Unger, TERMIS, 2018, 12, 1754. DOI: 10.1002/term.2703.
305. "One-Step Anionic Copolymerization Enables Formation of Linear Ultrahigh-Molecular-Weight Block Copolymer Films Featuring Vivid Structural Colors in the Bulk State",
M. Appold, E. Grune, H. Frey, M. Gallei, ACS Appl. Mater. Interfaces, 2018, 10, 18202. DOI: 10.1021/acsami.8b02848.
304. "Anionic Copolymerization Enables the Scalable Synthesis of Alternating (AB) n Multiblock Copolymers with High Molecular Weight in n/2 Steps"
E. Grune, M. Appold, A. H.E. Müller, M. Gallei, H. Frey, ACS Macro Lett., 2018, 7, 807. DOI: 10.1021/acsmacrolett.8b00390.
303. "One-Step Block Copolymer Synthesis versus Sequential Monomer Addition: A Fundamental Study Reveals That One Methyl Group Makes a Difference"
E. Grune, T. Johann, M. Appold, C. Wahlen, J. Blankenburg, D. Leibig, A. H. E. Müller, M. Gallei, H. Frey, Macromolecules, 2018,51, 3527. DOI: 10.1021/acs.macromol.8b00404.
302. "Comparison of Linear and Hyperbranched Polyether Lipids for Liposome Shielding by 18F-Radiolabeling and Positron Emission Tomography"
K. Wagener, M. Worm, S. Pektor, M. Schinnerer, Biomacromolecules, 2018, 19, 2506. DOI: 10.1021/acs.biomac.8b00115.
301. "Systematic Variation of the Degree of Branching (DB) of Polyglycerol via Oxyanionic Copolymerization of Glycidol with a Protected Glycidyl Ether and Its Impact on Rheological Properties"
C. Schubert, M. Schömer, M. Steube, S. Decker, C. Friedrich, H. Frey, Macromol. Chem. Phys. 2018, 219, 1700376. DOI: 10.1002/macp.201700376.
300. "Living Anionic Polymerization - Part II: Further Expanding the Synthetic Versatility for Novel Polymer Architectures"
H. Frey, T. Ishizone, Macromol. Chem. Phys. 2018, 219, 1700567. DOI: 10.1002/macp.201700567.

 

2017

Reviews

R32. "Die lebende anionische Polymerisation"
D. Leibig, J. Morsbach, E. Grune, J. Herzberger, A. H.E. Müller, H. Frey, Chemie in unserer Zeit 2017, 51, 254–263. DOI: 10.1002/ciuz.201700774.
R31. "Recent advances in the use of nanoparticles for allergen-specific immunotherapy"
H. Pohlit, I. Bellinghausen, H. Frey, J. Saloga, Allergy 2017, 72, 1461–1474. DOI: 10.1111/all.13199.

Original Contributions

299. "Well-Defined Multi-Amino-Functional and Stimuli-Responsive Poly(propylene oxide) by Crown Ether Assisted Anionic Ring-Opening Polymerization"
J. Blankenburg, M. Wagner, H. Frey, Macromolecules 2017, 50, 8885–8893. DOI: 10.1021/acs.macromol.7b01324.
298. "Living Anionic Polymerization Celebrates 60 Years: Unique Features and Polymer Architectures"
H. Frey, T. Ishizone, Macromol. Chem. Phys. 2017, 218, 1700217. DOI: 10.1002/macp.201700217.
297. "Silver Oxide Mediated Monotosylation of Poly(ethylene glycol) (PEG): Heterobifunctional PEG via Polymer Desymmetrization"
H. Pohlit, M. Worm, J. Langhanki, E. Berger-Nicoletti, T. Opatz, H. Frey, Macromolecules 2017, 50, 9196–9206. DOI: 10.1021/acs.macromol.7b01787.
296. "Poly(Ethylene Glycol) Dimethacrylates with Cleavable Ketal Sites: Precursors for Cleavable PEG-Hydrogels"
H. Pohlit, D. Leibig, H. Frey, Macromol. Biosci. 2017, 17, 1600532. DOI: 10.1002/mabi.201600532.
295. "Capillary Imbibition, Crystallization, and Local Dynamics of Hyperbranched Poly(ethylene oxide) Confined to Nanoporous Alumina"
Y. Yao, Y. Suzuki, J. Seiwert, M. Steinhart, H. Frey, H.-J. Butt, G. Floudas, Macromolecules 2017, 50, 8755–8764. DOI: 10.1021/acs.macromol.7b01843.
294. "Capitalizing on Protecting Groups to Influence Vinyl Catechol Monomer Reactivity and Monomer Gradient in Carbanionic Copolymerization"
D. Leibig, A.-K. Lange, A. Birke, H. Frey, Macromol. Chem. Phys. 2017, 218, 1600553. DOI: 10.1002/macp.201600553.
293. "Acid-Labile Surfactants Based on Poly(ethylene glycol), Carbon Dioxide and Propylene Oxide: Miniemulsion Polymerization and Degradation Studies"
M. Scharfenberg, S. Wald, F. R. Wurm, H. Frey, Polymers 2017, 9, 422. DOI: 10.3390/polym9090422.
292. "Examples of xylochemistry: Colorants and polymers"
J. Kühlborn, A.-K. Danner, H. Frey, R. Iyer, A. J. Arduengo, T. Opatz, Green Chem. 2017, 19, 3780–3786. DOI: 10.1039/C7GC01244F.
291. "Multiarm Polycarbonate Star Polymers with a Hyperbranched Polyether Core from CO 2 and Common Epoxides"
M. Scharfenberg, J. Seiwert, M. Scherger, J. Preis, M. Susewind, H. Frey, Macromolecules 2017, 50, 6577–6585. DOI: 10.1021/acs.macromol.7b01131.
290. "Rigid Hyperbranched Polycarbonate Polyols from CO 2 and Cyclohexene-Based Epoxides"
M. Scharfenberg, S. Hofmann, J. Preis, J. Hilf, H. Frey, Macromolecules 2017, 50, 6088–6097. DOI: 10.1021/acs.macromol.7b01276.
289. "Synthesis of linear polyglycerols with tailored degree of methylation by copolymerization and the effect on thermorheological behavior"
C. Schubert, P. Dreier, T. Nguyen, K. Maciol, J. Blankenburg, C. Friedrich, H. Frey, Polymer 2017, 121, 328–339. DOI: 10.1016/j.polymer.2017.05.030.
288. "Conducting Polymer with Orthogonal Catechol and Disulfide Anchor Groups for the Assembly of Inorganic Nanostructures"
B. Klöckner, K. Niederer, A. Fokina, H. Frey, R. Zentel, Macromolecules 2017, 50, 3779–3788. DOI: 10.1021/acs.macromol.7b00217.
287. "“Clickable PEG” via anionic copolymerization of ethylene oxide and glycidyl propargyl ether"
J. Herzberger, D. Leibig, J. Langhanki, C. Moers, T. Opatz, H. Frey, Polym. Chem. 2017, 8, 1882–1887. DOI: 10.1039/C7PY00173H.
286. "Thioether-Bearing Hyperbranched Polyether Polyols with Methionine-Like Side-Chains: A Versatile Platform for Orthogonal Functionalization"
J. Seiwert, J. Herzberger, D. Leibig, H. Frey, Macromol. Rapid Commun. 2017, 38, 1600457. DOI: 10.1002/marc.201600457.
285. "Pd@Fe 2 O 3 Superparticles with Enhanced Peroxidase Activity by Solution Phase Epitaxial Growth"
M. Kluenker, M. Nawaz Tahir, R. Ragg, K. Korschelt, P. Simon, T. E. Gorelik, B. Barton, S. I. Shylin, M. Panthöfer, J. Herzberger, H. Frey, V. Ksenofontov, A. Möller, U. Kolb, J. Grin, W. Tremel, Chem. Mater. 2017, 29, 1134–1146. DOI: 10.1021/acs.chemmater.6b04283.

2016

Reviews

R30.

"Polymerization of Ethylene Oxide, Propylene Oxide and Other Alkylene Oxides: Synthesis, Novel Polymer Architectures and Bioconjugation"
J. Herzberger, K. Niederer, H. Pohlit, J. Seiwert, M. Worm, F. R. Wurm, H. Frey, Chem. Rev. 2016, 116 (4), 2170-2243. DOI: 10.1021/acs.chemrev.5b00441.
Original Contributions

284.

“Cleavable Polyethylene Glycol (PEG): 3,4-Epoxy-1-butene (EPB) as a Comonomer to Establish Degradability at Physiologically Relevant pH"
M. Worm, D. Leibig, C. Dingels, H. Frey ACS Macro Lett., 2016, 5, 1357−1363.

283.

"Physicochemical and Preclinical Evaluation of Spermine-Derived Surfactant Liposomes for in Vitro and in Vivo siRNA-Delivery to Liver Macrophages"
Laura K. Müller, Leonard Kaps, Detlef Schuppan, Alexander Brose, Wenqiang Chai, Karl Fischer, Sophie Müller, Holger Frey, Manfred Schmidt, and Kristin Mohr , Mol. Pharmaceutics 2016, 13 (11), 3636–3647.

282.

"Can Hyperbranched Polymers Entangle? Effect of Hydrogen Bonding on Entanglement Transition and Thermorheological Properties of Hyperbranched Polyglycerol Melts"
Christian Schubert, Carina Osterwinter, Christoph Tonhauser, Martina Schömer, Daniel Wilms, Holger Frey, and Christian Friedrich, Macromolecules 2016, 49, 8722–8737.

281.

”Methods of protein surface PEGylation under structure preservation for the emulsion-based formation of stable nanoparticles"€
Radi, L ; Fach, M ; Montigny, M ; Berger-Nicoletti, E; Tremel, W; Wich, PR, MedChemComm 2016, 7, 1738-1744.

280.

”Biodegradable hyperbranched polyether-lipids with in-chain pH-sensitive linkages"
S. S. Müller, T. Fritz, M. Gimnich, M. Worm, M. Helm, H. Frey, Polym. Chem. 2016, 7, 6257-6268.

279.

”Conventional Oxyanionic versus Monomer-Activated Anionic Copolymerization of Ethylene Oxide with Glycidyl Ethers: Striking Differences in Reactivity Ratios"
J. Herzberger, D. Leibig, J. C. Liermann, H. Frey, ACS Macro Lett. 2016, 5, 1206-ˆ’1211.

278.

”Tunable dynamic hydrophobic attachment of guest molecules in amphiphilic core-shell polymers"
J. Reichenwallner, A. Thomas, L. Nuhn, T. Johann, A. Meister, H. Frey, D. Hinderberger, Polym. Chem. 2016, 7, 5783-5798.

277.

”Living Polymer Chains with Predictable Molecular Weight and Dispersity via Carbanionic Polymerization in Continuous Flow: Mixing Rate as a Key Parameter"
J. Morsbach, A. H. E. Müller, E. Berger-Nicoletti, H. Frey , Macromolecules 2016, 49, 5043-5050.

276.

”Orthogonal click conjugation to the liposomal surface reveals stability of lipid anchorage as crucial for targeting"
T. Fritz, M. Voigt, M. Worm, I. Negwer, S. S. Müller, K. Kettenbach, T. L. Ross, F. Roesch, K. Koynov, H. Frey, M. Helm, Chem. Eur J. 2016, 33, 11578-11582.

275.

”Copolymerization Kinetics of Glycidol and Ethylene Oxide, Propylene Oxide and 1,2-Butylene Oxide: From Hyperbranched to Multi-Arm Star Topology"
D. Leibig, J. Seiwert, J. C. Liermann, H. Frey, Macromolecules 2016, 49, DOI: 10.1021/acs.macromol.6b01477.

274.

”Thioether-Bearing Hyperbranched Polyether Polyols: A Versatile Platform for Orthogonal Functionalization"
J. Seiwert, J. Herzberger, D. Leibig, H. Frey, Macromol. Rapid Commun. 2016, DOI: 10.1002/marc.201600457.

273.

”Oxidation-responsive and ”clickable" poly(ethylene glycol) via copolymerization of 2-(methylthio)ethyl glycidyl ether"
J. Herzberger, K. Fischer, D. Leibig, M. Bros, R. Thiermann, H. Frey, J. Am. Chem. Soc. 2016, 138, 9212-9223.

272.

”Tailoring Novel PTFE Surface Properties: Promoting Cell Adhesion and Anti-fouling Properties via a Wet Chemical Approach"
M. Gabriel, K. Niederer, M.Becker, C. M. Raynaud, C.-F. Vahl, H. Frey, Bioconj. Chem. 2016, 27 (5), 1216-1221.

271.

”Anionic Polymerization of Vinylcatechol Derivatives: Reversal of the Monomer Gradient Directed by the Position of the Catechol Moiety in the Copolymerization with Styrene”
D. Leibig, A. H. E. Müller, H. Frey, Macromolecules 2016, 49, 4792-4801.

270.

”Could allergen-specific immunotherapy benefit from the use of nanocarriers?"
H. Pohlit, H. Frey, J. Saloga, Nanomedicine 2016, 11 (11), 1329-1331.

269.

”Hierachical Ni@Fe2O3 superparticles through epitaxial growth of γ-Fe2O3 nanorods on in situ formed Ni nanoplates"
M. N. Tahir, J. Herzberger, F. Natalio, O. Köhler, R. Branscheid, E. Mugnaioli, V. Ksenofontov, M. Panthöfer, U. Kolb, H. Frey W. Tremel, Nanoscale 2016, 8 (18), 9548-9555.

268.

”Polyvinylferrocene-Based Amphiphilic Block Copolymers Featuring Functional Junction Points for Cross-Linked Micelles"
J. Morsbach, J. Elbert, C. Rüttiger, S. Winzen, H. Frey, M. Gallei, Macromolecules 2016, 49, 3406-3414.

267.

”Acid-Labile Amphiphilic PEO-b-PPO-b-PEO Copolymers: Degradable Poloxamer Analogs"€
M. Worm, B. Kang, C. Dingels, F. R. Wurm, H. Frey, Macromol. Rapid Commun. 2016, 37, 775-780.

266.

”Poly(THF-co-cyano ethylene oxide): Cyano Ethylene Oxide (CEO) Copolymerization with THF Leading to Multifunctional and Water-Soluble PolyTHF Polyelectrolytes"€
E. M. Christ, J. Herzberger, M. Montigny, W. Tremel, H. Frey, Macromolecules 2016, 49, 3681-3695.

265.

”Processing and Adjusting the Hydrophilicity of Poly(oxymethylene) (Co)polymers: Nanoparticle Preparation and Film Formation"
M. B. Bannwarth, R. Klein, S. Kurch, H. Frey, K. Landfester, F. R. Wurm, Polym. Chem. 2016, 7, 184 - 190.

264.

”Catechol-acetonide glycidyl ether (CAGE): A Functional Epoxide Monomer for Linear and Hyperbranched Multi-Catechol Functional Polyether Architectures"
K. Niederer, C. Schüll, D. Leibig, T. Johann, H. Frey, Macromolecules 2016, 49 (5), 1655-1665.

263.

”Hyperbranched Polyols via Copolymerization of 1,2-Butylene Oxide and Glycidol: Comparison of Batch Synthesis and Slow Monomer Addition"€
J. Seiwert, D. Leibig, U. Kemmer-Jonas, M. Bauer, I. Perevyazko, J. Preis, H. Frey, Macromolecules 2016, 49 (1), 38-47.

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2015

Original Contributions

262.

”Controllable Nonspecific Protein Adsorption by Charged Hyperbranched Polygly­cerol Thin Films"
Y. Yu, H. Frey, Langmuir 2015, 31, 13101-13106.

261.

„Epicyanohydrin: Polymerization by Monomer Activation gives Access to Nitrile, Amino and Carboxyl-Functional Poly(ethylene glycol)"
J. Herzberger, H. Frey, Macromolecules 2015, 48, 8144-8153.

260.

”Unusual triskelion patterns and dye-labelled GUVs: Consequences of the interaction of cholesterol-containing linear-hyperbranched block copolymers with phospholipids"€
P. Scholtysek, S. W. H. Shah, S. S. Müller, R. Schöps, H. Frey, A. Blume, J. Kressler, Soft Matter 2015, 11, 6106-6117.

259.

”Maleimide Glycidyl Ether: A Bifunctional Monomer for Orthogonal Cationic and Radical Polymerizations"
R, Klein, F. Übel, H. Frey, Macromol. Rapid Commun. 2015, 36, 1822-1828.

258.

”Statistical properties of linear-hyperbranched graft copolymers prepared via "hypergrafting"€ of ABm monomers from linear B-functional core chains: A Molecular Dynamics simulation”
H. Rabbel, H. Frey, F. Schmid, The Journal of Chemical Physics 2015, 143, 243125.

257.

”Transformation of vaterite nanoparticles to hydroxycarbonate apatite in a hydrogel scaffold: relevance to bone formation”
R. Schröder, H. Pohlit, T. Schüler, M. Panthöfer, R. E. Unger, H. Frey, W. Tremel, J. Mater. Chem. B 2015, 3, 7079-7089.

256.

”Enhanced immunogenicity of multivalent MUC1 glycopeptide antitumour vaccines based on hyperbranched polymers"€
M. Glaffig, B. Palitzsch, N. Stergiou, C. Schüll, D. Straßburger, E. Schmitt, H. Frey, H. Kunz, Org. Biomol. Chem. 2015, 13, 10150-10154.

255.

”Hyperbranched Poly(ethylene glycol) Copolymers: Absolute Values of the Molar Mass, Properties in Dilute Solution, and Hydrodynamic Homology"
I. Perevyazko, J. Seiwert, M. Schömer, H. Frey, U. S. Schubert, G. M. Pavlov, Macromolecules 2015, 48, 5887-5898.

254.

”Water-soluble and redox-responsive hyperbranched polyether copolymers based on ferrocenyl glycidyl ether"€
A. Alkan, R. Klein, S. I. Shylin, U. Kemmer-Jonas, H. Frey, F. R. Wurm, Polym. Chem. 2015, 6, 7112-7118.

253.

”Biodegradable pH-Sensitive Poly(ethylene glycol) Nanocarriers for Allergen Encapsulation and Controlled Release"
H. Pohlit, I. Bellinghausen, M. Scho¨mer, B. Heydenreich, J. Saloga, H. Frey, Biomacromolecules 2015, 16, 3103-3111.

252.

”Cationic Copolymerization of 3,3-Bis(hydroxymethyl)oxetane and Glycidol: Biocompatible Hyper­branched Polyether Polyols with High Content of Primary Hydroxyl Groups"
E.-M. Christ, D. Hobernik, M. Bros, M. Wagner, H. Frey, Biomacromolecules 2015, 16, 3197-3307.

251.

”Fate of Linear and Branched Polyether-Lipids in vivo in Comparison to their Liposomal Formulations by 18F-Radiolabeling and Positron Emission Tomography"€
A. T. Reibel, S. S. Müller, S. Pektor, N. Bausbacher, M. Miederer, H. Frey, F. Rösch, Biomacromolecules 2015, 16, 842-851.

250.

„Hyperbranched poly(glycolide) copolymers with glycerol branching points via ring-opening copolymerization"
A. M. Fischer, C. Schüll, H. Frey, Polymer 2015, 72, 436-446.

249.

„Aliphatic Polycarbonates Based on Carbon Dioxide, Furfuryl Glycidyl Ether, and Glycidyl Methyl Ether: Reversible Functionalization and Cross-Linking”
J. Hilf, M. Scharfenberg, J. Poon, C. Moers, H. Frey, Macromol. Rapid Commun. 2015, 36, 174-179.

248.

”Rheological Consequences of Hydrogen Bonding: Linear Viscoelastic Response of Linear Polyglycerol and Its Permethylated Analogues as a General Model for Hydroxyl-Functional Polymers"
C. Osterwinter, C. Schubert, C. Tonhauser, D. Wilms, H. Frey, C. Friedrich, Macromolecules 2015, 48, 119-130.

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2014

Reviews

R29

"Beyond Poly(ethylene glycol): Linear Polyglycerol as a Multifunctional Polyether for Biomedical and Pharmaceutical Applications"
A. Thomas, S. S. Müller, H. Frey, Biomacromolecules 2014, 15, 1935-1954. DOI: 10.1021/bm5002608.
Original Contributions

247.

”Vinylphenylglycidyl ether-based colloidal architectures: high-functionality crosslinking reagents, hybrid raspberry-type particles and smart hydrophobic surfaces”
S. Mehlhase, C. G. Schäfer, J. Morsbach, L. Schmidt, R. Klein, H. Frey, M. Gallei, RSC Adv., 2014, 4, 41348-41352.

246.

”Evaluation of Multifunctional Liposomes in Human Blood Serum by Light Scattering"€
K. Mohr, S. S. Müller, L. K. Müller, K. Rusitzka, S. Gietzen, H. Frey, M. Schmidt, Langmuir 2014, 30, 14954-14962.

245.

”Supramolecular Antioxidant Assemblies of Hyperbranched Polyglycerols and Phenols"
S. Pocoví-Martínez , U. Kemmer-Jonas , J. Pérez-Prieto, H. Frey , S.-E. Stiriba, Macromol. Chem. Phys. 2014, 215, 2311-2317.

244.

”Stimuli-Responsive Tertiary Amine Functional PEGs Based on N,N-Dialkyl-glycidylamines"€
J. Herzberger, D. Kurzbach, M. Werre, K. Fischer, D. Hinderberger, H. Frey, Macromolecules, 2014, 47, 7679-7690.

243.

"A Challenging Comonomer Pair: Copolymerization of Ethylene Oxide and Glycidyl Methyl Ether to Thermoresponsive Polyethers"
S. S. Müller, C. Moers, H. Frey, Macromolecules 2014, 47, 5492-5500.

242.

"Living Anionic Polymerization in Continuous Flow: Facilitated Synthesis of High Molecular Weight Poly(2-vinyl pyridine) and Polystyrene"
A. Natalello, J. Morsbach, A. Friedel, A. Alkan, C. Tonhauser, A. H. E. Müller, H. Frey, Org. Process Res. Dev. 2014, 18, 1408-1412.

241.

"Hydroxyfunctional Oxetane-Inimers with Varied Polarity for the Synthesis of Hyperbranched Polyether Polyols via Cationic ROP"
E.-M. Christ, S. S. Müller, E. Berger-Nicoletti,, H. Frey, J. Polym. Sci. Polym. Chem. 2014, 52, 2850-2859.

240.

"Cytotoxicity and Chemosensitizing Activity of Amphiphilic Poly(glycerol)-Poly(alkylene oxide) Block Copolymers"
T. V. Demina, O. A. Budkina, G. A. Badun, N. S. Melik-Nubarov, H. Frey, S. S. Müller, J. Nieberle, I. D. Grozdova, Biomacromolecules 2014, 15, 2672-2681. [Link].

239.

"Click Modification of Multifunctional Liposomes Bearing Hyperbranched Polyether Chains"
T. Fritz, M. Hirsch, F. C. Richter, S. S. Müller, A. M. Hofmann, K. A. K. Rusitzka, J. Markl, U. Massing, H. Frey, M. Helm, Biomacromolecules 2014, 15, 2440-2448. [Link].

238.

"The ”Needle in the Haystack€" Makes the Difference: Linear and Hyperbranched Polyglycerols with a Single Catechol Moiety for Metal Oxide Nanoparticle Coating"
A. Thomas, H. Bauer, A.-M. Schilmann, K. Fischer, W. Tremel, H. Frey, Macromolecules 2014, 47, 4557-4566. [Link.

237.

"Functional Group Distribution and Gradient Structure Resulting from the Living Anionic Copolymerization of Styrene and para-But-3-enyl Styrene"
A. Natalello, A. Alkan, P. von Tiedemann, F. R. Wurm, H. Frey, ACS Macro Lett. 2014, 3, 560-564.

236.

"Ferrocene-Containing Multifunctional Polyethers: Monomer Sequence Monitoring via Quantitative 13C NMR Spectroscopy in Bulk"
A. Alkan, A. Natalello, M. Wagner, H. Frey, F. R. Wurm, Macromolecules 2014, 47, 2242-2249.

235.

"A Convenient Approach to Amphiphilic Hyperbranched Polymers with Thioether Shell for the Preparation and Stabilization of Coinage Metal (Cu, Ag, Au) Nanoparticles"
S. Skaria, R. Thomann, C. J. Gómez-Garcia, L. Vanmaele, J. Loccufier, H. Frey, S.-E. Stiriba, J. Polym. Sci. Polym. Chem. 2014, 52, 1369-1375.

234.

”A Fully Synthetic Glycopeptide Antitumour Vaccine Based on Multiple Antigen Presentation on Hyperbranched Polymer"
Glaffig, B. Palitzsch, S. Hartmann, C. Schüll, L. Nuhn, B. Gerlitzki, E. Schmitt, H. Frey, H. Kunz, Chem. Eur. J. 2014, 20, 4232-4236.

233.

"Graft Copolymers with Complex Polyether Structures: Poly(ethylene oxide)-graft-Poly(isobutyl vinyl ether) by Combination of Living Anionic and Photo-induced Cationic Graft-Polymerization"
M. U. Kahveci, C. Mangold, H. Frey, Y. Yagci, Macromol. Chem. Phys. 2014, 215, 566-571.

232.

"Poly(carbonate) Copolymers with Tailored Number of Hydroxyl Groups from Glycidyl Ethers and CO2"
J. Hilf, A. Phillips, H. Frey, Polym. Chem. 2014, 5, 814-818.

231.

"Combining oxyanionic polymerization and click chemistry: a general strategy for the synthesis of polyether polyol macromonomers"
A. Thomas, K. Niederer, F. Wurm, H. Frey, Polym. Chem. 2014, 5, 899-909.

230.

"Controlled Synthesis of Multi-Arm Star Polyether-Polycarbonate Polyols Based on Propylene Oxide and CO2"
J. Hilf, P. Schulze, J. Seiwert, H. Frey, Macromol. Rapid Commun. 2014, 35, 198-203.

229.

”(1-Adamantyl)methyl Glycidyl Ether: A Versatile Building Block for Living Polymerizations"
Christian Moers, Robert Wrazidlo, Adrian Natalello, Isabelle Netz, Mihail Mondeshki, Holger Frey, Macromol Rapid Commun. 2014, 35, 1075-1080.

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2013

Reviews

R28

"Polyether-Based Lipids Synthesized with an Epoxide Construction Kit: Multivalent Architectures for Functional Liposomes"
S. S. Müller, C. Dingels, A. M. Hofmann, H. Frey, ”Tailored Polymer Architectures for Pharmaceutical and Biomedical Applications"€, ACS Books; Chapter 2 2013, 11-25. DOI: 10.1021/bk-2013-1135.ch002.

R27

”Grafting of Hyperbranched Polymers: From Unusual Complex Polymer Topologies to Multivalent Surface Functionalization"€
C. Schüll, H. Frey, Polymer 2013, 54, 5443-5455. DOI: 10.1016/j.polymer.2013.07.065.

R26

"From Biocompatible to Biodegradable: Poly(ethylene glycol)s with In-Chain Cleavable Linkages"
C. Dingels, H. Frey Adv. Polym. Sci. 2013, 262, 167-190. DOI: 10.1007/12_2013_235.

R25

"Aminofunctional Polyethers: Smart Materials For Applications in Solution and on Surfaces"
V. S. Wilms, H. Frey, Polym. Int. 2013, 62, 849-859. DOI: 10.1002/pi.4496.

R24

"Hyperbranched Aliphatic Polyether Polyols"
M. Schömer, C. Schüll, H. Frey J. Polym. Sci. A, Polym. Chem. 2013, 51, 995-1019. DOI: 10.1002/pola.26496.
Original Contributions

228.

"Micellar interactions in water-AOT based droplet microemulsions containing hydrophilic and amphiphilic polymers"
Markus Appel, Tinka Luise Spehr, Robert Wipf, Christian Moers, Holger Frey, Bernd Stühn, J. Chem. Phys. 2013, 139, 184903.

227.

"Supramolecular Linear-g-hyperbranched Graft Polymers: Topology and Binding Strength of Hyperbranched Side-Chains"
C. Moers, L. Nuhn, M. Wissel, R. Stangenberg, M. Mondeshki, E Berger-Nicoletti, A. Thomas, D. Schaeffel, K. Koynov, M. Klapper, R. Zentel, H. Frey, Macromolecules 2013, 46, 9544-9553.

226.

"CO2-Based Nonionic Surfactants: Solvent-Free Synthesis of Poly(ethylene glycol)-b-Poly(propylene carbonate) Block Copolymers"
J. Hilf, P. Schulze, H. Frey, Macromol. Chem. Phys. 2013, 214, 2848-2855.

225.

"Monomer Sequence Distribution Monitoring in Living Carbanionic Copolymerization by Real-Time 1H NMR Spectroscopy"
A. Natalello, M. Werre, A. Alkan, H. Frey, Macromolecules 2013, 46, 8467-8471.

224.

"ABA Triblock Copolymers Based on Linear Poly(oxymethylene) and Hyperbranched Poly(glycerol): Combining Polyacetals and Polyethers"
R. Klein, C. Schüll, M. Haubs, K. Kurz, H. Frey, Macromolecules 2013, 46, 8845-8852.

223.

"Redox-Responsive Block Copolymers: Poly(vinylferrocene)-b-Poly(lactide) Diblock and Miktoarm Star Polymers and their Behavior in Solution"
J. Morsbach, A. Natalello, J. Elbert,S. Winzen, A. Kroeger, H. Frey, M. Gallei, Organometallics 2013, 32, 6033-6039.

222.

"Block copolymers in giant unilamellar vesicles with proteins or with phospholipids"
R. Schöps, E. Amado, S. S. Müller, H. Frey, J. Kressler, Faraday Discussions 2013, 166, 303-315.

221.

"Directing the Self-Assembly of Semiconducting Copolymers: The Consequences of Grafting Linear or Hyperbranched Polyether Side Chains"
L. zur Borg, C. Schüll, H. Frey, R. Zentel, Macromol. Rapid Commun. 2013, 34, 1213-1219.

220.

"Glycidyl-Propargyl-functional Aliphatic Polycarbonate Obtained from Carbon Dioxide and GlycidylPropargyl Ether"
J. Hilf, H. Frey, Macromol. Rapid Commun. 2013, 34, 1395-1400.

219.

"Polydispersity and Molecular Weight Distribution of Hyperbranched Graft-Copolymers via ”Hypergrafting" of ABm Monomers from Polydisperse Macroinitiator Cores: Theory Meets Synthesis"
C. Schüll, H. Rabbel, F. Schmid, H. Frey, Macromolecules. 2013, 46, 5823-5830.

218.

"One-step synthesis of multi-alkyne functional hyperbranched polyglycerols by copolymerization of glycidyl-propargyl ether and glycidol"
C. Schüll, T. Gieshoff, H. Frey, Polym. Chem. 2013, 4, 4730 - 4736.

217.

"Anionic Polymerization of para(1-ethoxy ethoxy)styrene (pEES): Rapid Access to Poly(p-hydroxystyrene) Copolymer Architectures"
A. Natalello, C. Tonhauser, H. Frey, ACS Macro Lett. 2013, 2, 409-413.

216.

"Stereocomplex Formation in Polylactide Multi-Arm Stars and Comb-Copolymers with Linear and Hyperbranched Multifunctional PEG"
J. Geschwind, S. Rathi, C. Tonhauser, M. Schömer, S. L. Hsu, E. B. Coughlin, H. Frey, Macromol. Chem. Phys. 2013, 214, 1434-1444.

215.

"Poly(1,2-glycerol carbonate): A Fundamental Polymer Structure Synthesized from CO2 and Glycidyl ethers"
J. Geschwind, H. Frey, Macromolecules, 2013, 46, 3280-3287.

214.

"Enlarging the Toolbox: Epoxide Termination of Polyferrocenylsilane (PFS) as a Key Step for the Synthesis of Amphiphilic PFS-Polyether Block Copolymers"
A. Natalello, A. Alkan, A. Friedel, I. Lieberwirth, H. Frey, F. R. Wurm, ACS Macro Lett. 2013, 2, 313-316.

213.

"Combining Ring-Opening Multibranching and RAFT Polymerization: Multifunctional Linear-Hyperbranched Block Copolymers via Hyperbranched Macro Chain Transfer Agents"
L. Nuhn, C. Schüll, H. Frey, R. Zentel, Macromolecules 2013,46, 2892-2904.

212.

"Impact of Amino-Functionalization on the Response of Poly(ethylene glycol) (PEG) to External Stimuli"
D. Kurzbach, V. S. Wilms, H. Frey, D. Hinderberger, ACS Macro Lett. 2013, 2, 128-131.

211.

"Ferrocenyl Glycidyl Ether: A Versatile Ferrocene Monomer for Copolymerization with Ethylene Oxide to Water-Soluble, Thermo-Responsive Copolymers"
C. Tonhauser, A. Alkan, M. Schömer, C. Dingels, M. Schömer, S. Ritz, V. Mailänder, H. Frey, F. R. Wurm, Macromolecules 2013, 46, 647-655.

210.

"From CO2-Based Multifunctional Polycarbonates With a Controlled Number of Functional Groups to Graft Polymers"
J. Geschwind, F. R. Wurm, H. Frey, Macromol. Chem. Phys. 2013, 214, 892-901.

209.

"Electrocatalytical Properties of Carbosilane-Based Hyperbranched Polymers Functionalized with Interacting Ferrocenyl Units"
G. de la Cruz, H. Schüle, J. Losada, M. P. García-Armada, H. Frey. B. Alonso, C. M. Casado, Eur. J. Inorg. Chem. 2013, 44-53.

208.

"A Universal Concept for the Implementation of a Single Cleavable Unit at Tunable Position in Functional Poly(ethylene glycol)s"
C. Dingels, S. S. Müller, T. Steinbach, C. Tonhauser, H. Frey, Biomacromolecules 2013, 14, 448-459.

207.

"One-Pot Synthesis of Poly(L-lactide) Multi-Arm Star Copolymers Based on a Polyester Polyol Macroinitiator"
A. M. Fischer, R. Thiermann, M. Maskos, H. Frey, Polymer 2013, 54, 1993-2000.

206.

"Catechol-Initiated Polyethers: Multifunctional Hydrophilic Ligands for PEGylation and Functionalization of Metal Oxide Nanoparticles"
V. S. Wilms, H. Bauer, C. Tonhauser, A.-M. Schilmann, M.-C. Müller, W. Tremel, H. Frey, Biomacromolecules 2013, 14, 193-199.

205.

"Stable, Hydroxyl-Functional Polycarbonates with Glycerol Side Chains Synthesized from CO2 and Isopropylidene(glyceryl glycidyl ether)"
J. Geschwind, H. Frey, Macromol. Rapid Commun. 2013, 34, 150-155.

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2012

Reviews

R23

"Micro-Flow Technology in Polymer Synthesis"
C. Tonhauser, A. Natalello, H. Löwe, H. Frey, Macromolecules 2012, 45, 9551-9570 (Invited Perspectives-Article). DOI: 10.1021/ma301671x.

R22

"Functional PEG-based polymers with reactive groups via anionic ROP of tailor-made epoxides"
C. Mangold, F. Wurm, H. Frey, Polymer Chemistry 2012, 3 (7), 1714-1721. DOI: 10.1039/C2PY00489E.

R21

"Nonlinear Macromolecules by Ring-Opening Polymerization"
Schüll, C.; Wilms, D.; Frey, H.; In: Matyjaszewski, K. and Möller, M. (eds.) Polymer Science: A Comprehensive Reference, 2012, Vol. 4, pp. 571-596, Amsterdam: Elsevier BV. DOI: 10.1016/B978-0-444-53349-4.00118-7.

R20

" Hyperbranched Polymers: Synthetic Methodology, Properties, and Complex Polymer Architectures"
Wurm, F.; Frey, H.; In: Matyjaszewski, K. and Möller, M. (eds.), Polymer Science: A Comprehensive Reference, 2012, Vol. 6, pp. 177-198, Amsterdam: Elsevier BV. DOI: 10.1016/B978-0-444-53349-4.00163-1.
Original Contributions

204.

"How Structure-Related Collapse Mechanisms Determine Nanoscale Inhomogeneities in Thermoresponsive Polymers"
D. Kurzbach, M. Schömer, V. S. Wilms, H. Frey, D. Hinderberger, Macromolecules, 2012, 45, 7535-7548.

203.

"Squaric Acid Mediated Chemoselective PEGylation of Proteins: Reactivity of Single-Step Activated a.Amino Poly(ethylene glycol)s"
C. Dingels, F. Wurm, M. Wagner, H.-A. Klok, H. Frey, Chem. Eur. J. 2012, 18, 16828-16835.

202.

"Branched Acid-Degradable, Biocompatible Polyether-Based Copolymers by Anionic Ring-Opening Polymerization Using an Epoxide Inimer"
C. Mangold, C. Schüll, C. Dingels, H. Frey, ACS Macro Lett. 2012, 1, 1094-1097.

201.

"Hyperbranched Poly(propylene oxide): A Multifunctional Backbone-Thermoresponsive Polyether-Polyol Copolymer"
M. Schömer, J. Seiwert, H. Frey, ACS Macro Lett. 2012, 1, 888-891.

200.

"Synthesis of Oxetane-Functional Aliphatic Polyesters via Enzymatic Polycondensation"
S. S. Müller, H. Frey, Macromol. Chem. Phys. 2012, 213, 1783-1790.

199.

"Stimuli-Responsive Y-Shaped Polymer Brushes Based on Junction-Point Reactive Block Copolymers"
C. Tonhauser, A. A. Golriz, C. Moers, R. Klein, H.-J. Butt, H. Frey, Adv. Mater. 2012, 24, 5559-5563.

198.

"Linear-Hyperbranched Graft-Copolymers via the Grafting-to Strategy Based on Hyperbranched Dendron Analogues and Reactive Ester Polymers"
C. Schüll, L. Nuhn, C. Mangold, E. Christ, R. Zentel, H. Frey, Macromolecules 2012, 45, 5901-5910.

197.

"Polysiloxane-Backbone Block Copolymers in a One-Pot Synthesis: A Silicone Platform for Facile Functionalization"
P. Boehm, M. Mondeshki, H. Frey, Macromol.Rapid Commun. 2012, 33, 1861-1867.

196.

"Thermoresponsive Copolymers of Ethylene Oxide and N,N-Diethyl Glycidyl Amine: Polyether Polyelectrolytes and PEGylated Gold Nanoparticle Formation"
V. S. Reuss, M. Werre, H. Frey, Macromol. Rapid Commun. 2012, 33, 1556-1561.

195.

"P(HPMA)-block-P(LA) copolymers in paclitaxel formulations: Polylactide stereochemistry controls micellization, cellular uptake kinetics, intracellular localization and drug efficiency"
M. Barz, A. Armiñán, F. Canal, F. K. Wolf, K. Koynov, H. Frey, R. Zentel, M. J. Vicent, J. Controlled Release 2012, 163(1), 63-74.

194.

"Long-Chain Branched Poly(lactide)s based on Polycondensation of AB2-type Macromonomers"
A. M. Fischer, F. K. Wolf, H. Frey, Macromol. Chem. Phys. 2012, 213, 1349-1358.

193.

"Dendritic Polymers - Universal Glue for Cells" (News and Views Article)
H. Frey, Nature Materials 2012, 11, 359-360.

192.

"N,N-Diallyl Glycidyl Amine: A Key Monomer for Aminofunctional Poly(ethylene glycol) Architectures"
V. S. Reuss, B. Obermeier, C. Dingels, H. Frey, Macromolecules 2012, 45, 4581-4589.

191.

"Squaric Acid Mediated Synthesis and Biological Activity of a Library of Linear and Hyperbranched Poly(Glycerol)-Protein Conjugates"
F. Wurm, C. Dingels, H. Frey, H.-A. Klok, Biomacromolecules 2012, 13, 1161-1171.

190.

"Controlled Synthesis of Linear Polymers with Highly Branched Side Chains by ”Hypergrafting"€: Poly(4?hydroxy styrene)?graft?hyperbranched Polyglycerol"
C. Schüll, H. Frey, ACS Macro Lett. 2012, 1, 461-464.

189.

"Water-Soluble ”Poly(propylene oxide)" by Random Copolymerization of Propylene Oxide with a Protected Glycidol Monomer"
M. Schömer, H. Frey, Macromolecules 2012, 45, 3039-3046.

188.

"Water-Soluble Poly(vinylferrocene)-b-Poly(ethylene oxide) Diblock and Miktoarm Star Polymers"
C. Tonhauser, M. Mazurowski, M. Rehahn, M. Gallei, H. Frey, Macromolecules 2012,45, 3409-3418.

187.

"Mixed layers of DPPC and a linear poly(ethylene glycol)-b-hyperbranched poly(glycerol) block copolymer having a cholesteryl end group"
X. Peng, A. M. Hofmann, S. Reuter, H. Frey, J. Kressler, Colloid Polym. Sci. 2012, 290, 579-588.

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2011

Book

B6

Edited book: "Hyperbranched Polymers: Syntheses, Properties and Applications"
D. Yan, C. Gao, H. Frey Eds.; 2011, J. Wiley Publishers, New York and London

Links: [Wiley] [Amazon]

Reviews

R19

"Von der Kosmetik zum Ionenleiter: Die vielen Gesichter des Poly(ethylenglykols)"
Chemie in unserer Zeit, C. Dingels, M. Schömer, H. Frey, 2011, 45, 338-349. DOI: 10.1002/ciuz.201100551.

R18

"Multifunctional Poly(ethylene glycol)s"
B. Obermeier, F. Wurm, C. Mangold, H. Frey, Angew. Chem. Int. Ed.2011, 50, 7988 - 7997. DOI: 10.1002/anie.201100027.

"Multifunktionelle Poly(ethylenglycole)"
B. Obermeier, F. Wurm, C. Mangold, H. Frey, Angew. Chem. 2011, 123, 8136 - 8146. DOI: 10.1002/ange.201100027.

R17

"Linear-Dendritic Block Copolymers: The State of the Art and Exciting Perspectives"
F. Wurm, H. Frey, Prog. Polym. Sci. 2011, 36, 1-52. DOI: 10.1016/j.progpolymsci.2010.07.009.
Original Contributions

186.

"A Combined DPE/Epoxide Termination Strategy for Hydroxyl End-Functional Poly(2-vinylpyridine) and Amphiphilic AB2-Miktoarm Stars"
A. Natalello, C. Tonhauser, E. Berger-Nicoletti, H. Frey, Macromolecules 2011, 44, 9887-9890.

185.

"Oligo(glycerol) Methacrylate Macromonomers"
A. Thomas, F. K. Wolf, H. Frey, Macromol. Rapid Commun. 2011, 32, 1910-1915.

184.

"From an Epoxide Monomer Toolkit to Functional PEG Copolymers with Adjustable LCST Behavior"
C. Mangold, B. Obermeier, F. Wurm, H. Frey, Macromol. Rapid Commun. 2011, 32, 1930-1934.

183.

"Organobase-Catalyzed Synthesis of Multi-Arm Star Polylactide with Hyperbranched Poly(ethylene glycol) as a Core"
M. Schömer, H. Frey, Macromol. Chem. Phys. 2011, 212, 2478-2486.

182.

"Interaction between a water-in-oil microemulsion and a linear-dendritic poly(propylene oxide)-polyglycerol block copolymer"
R. Wipf, M. Kraska, T. Spehr, J. Nieberle, H. Frey, B. Stühn, Soft Matter 2011, 7, 10879-10888.

181.

"Mesogen-Initiated Linear Polyglycerol Isomers: The Ordering Effect of a Single Cholesterol Unit on ”Sticky" Isotropic Chains"
A. M. Hofmann, R. Wipf, B. Stühn, H. Frey Macromolecules 2011, 44, 6767-6775.

180.

"Synthesis of Water-Soluble Copolymers Carrying Long-Chain (C12 to C30) AliphaticMoieties"
F. Barroso-Bujans, M. Yazdani-Pedram, H. Frey, R. Martinez Macromol. Chem. Phys. 2011, 212, 1648-1653.

179.

"PEG-based Multifunctional Polyethers with Highly Reactive Vinyl-Ether Side Chains for Click-Type Functionalization"
C. Mangold, C. Dingels, B. Obermeier, H. Frey, F. Wurm, Macromolecules 2011, 44, 6326-6334.

178.

"Introducing an Amine Functionality at the Block Junction of Amphiphilic Block Copolymers by Anionic Polymerization Strategies"
C. Tonhauser, B. Obermeier, C. Mangold, H. Löwe, H. Frey, Chem. Commun. 2011, 47, 8964-8966.

177.

"The phase behavior of the system linear polyglycerol + methanol + carbon dioxide"
C. S. Schacht, C. Schuell, H. Frey, T.W. de Loos, J. Gross, J. Chem. Eng. Data 2011, 56, 2927-2931.

176.

"Rapid Access to Polyfunctional Lipids with Complex Architecture via Oxyanionic Ring-Opening Polymerization"
A. M. Hofmann, F.Wurm, H. Frey, Macromolecules 2011, 44, 4648-4657.

175.

"Correlations between Ion Conductivity and Polymer Dynamics in Hyperbranched Poly(ethylene oxide) Electro­lytes for Lithium Ion Batteries"
S.-I. Lee, M. Schömer, H. Peng, K. A. Page, D. Wilms, H. Frey, C. L. Soles, D. Y. Yoon, Chem. Mater. 2011, 23, 2685-2688.

174.

"Poly(ethylene glycol-co-allyl glycidyl ether)s: A PEG-Based Modular Synthetic Platform for Multiple Bioconjugation"
B. Obermeier, H. Frey, Bioconjugate Chemistry 2011, 22, 436-444.

173.

"Towards the Generation of Self-healing Materials by Means of a Reversible Photo-induced Approach"
P. Froimowicz, H. Frey, K. Landfester, Macromol. Rapid Commun. 2011, 32, 468-473.

172.

"Langmuir and Langmuir-Blodgett Films of Multifunctional, Amphiphilic Polyethers with Cholesterol Moieties"
S. Reuter, A. M. Hofmann, K. Busse, H. Frey, J. Kressler, Langmuir 2011, 27, 1978-1989.

171.

"Partially Quarternized Amino Functional Poly(methacrylate) Terpolymers: Versatile Drug Permeability Modifiers"
B. Obermeier, P. Langguth, Peter; H. Frey, Biomacromolecules 2011, 12, 425-431.

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2010

170.

"Phase behavior of the system hyperbranched polyglycerol + methanol + carbon dioxide"
C. S. Schacht, S. Bahramali, D. Wilms, H. Frey, J. Gross, T. W. de Loos, Fluid Phase Equlibria 2010, 299, 252-258.

169.

"Entanglement Transition in Hyperbranched Polyether-Polyols"
C. Tonhauser, D. Wilms, Y. Korth, H. Frey, C. Friedrich, Macromol. Rapid Commun. 2010, 31, 2127-2132.

168.

"Soluble Hyperbranched Polyglycolide Copolymers"
A. M. Fischer, H. Frey, Macromolecules 2010, 43, 8539-8548.

167.

"Multihydroxy-Functional Polysilanes via an Acetal Protecting Group Strategy"
V. S. Reuss, H. Frey, Macromolecules 2010, 43, 8462-8467.

166.

"Chiroptical Induction and Molecular Recognition in Optically Active Hyper­bran­­ched Polyethers with Inherently Chiral Benzophenone Core"
L. Pastor-Pérez, U. Kemmer-Jonas, F. Wurm, S.-E. Stiriba, J. Pérez-Prieto, H. Frey, Macromolecules 2010, 43, 9583-9587.

165.

"Functional Poly(ethylene glycol) ": PEG-Based Random Copolymers with 1,2-Diol Side Chains and Terminal Amino Functionality"
C. Mangold, F. Wurm, B. Obermeier, H. Frey, Macromolecules 2010, 43, 8511-8518.

164.

"Poly(glycolide) multi-arm star polymers: Improved solubility via limited arm length"
F. K. Wolf, A. M. Fischer, H. Frey, Beilstein J. Org. Chem. 2010, 6, No. 67, doi:10.3762/bjoc.6.67.

163.

"Multihydroxyl-Functional Polystyrenes in Continuous Flow"
C. Tonhauser, D. Wilms, F. Wurm, E. Berger-Nicoletti, M. Maskos, H. Löwe, H. Frey, Macro­molecules 2010, 43, 5582-5588.

162.

"Branched versus linear oligo(dimethylsiloxane): Differences in their thermo­dynamic interaction with solvents"
F. Samadi, J. Eckelt, B. A. Wolf, H. Schüle, H. Frey, J. Polym. Sci. B Polym. Phys., 2010, 48, 1309-1318.

161.

"Poly(isoglycerol methacrylate)-b-poly(D- or L-lactide) Copolymers: A Novel Hydrophilic Methacrylate as Building Block for Supramolecular Aggregates"
F. K. Wolf, A. M. Hofmann, H. Frey, Macromolecules 2010, 43, 3314-3324.

160.

"Hyperbranched PEG by Random Copolymerization of Ethylene Oxide and Glycidol"
D. Wilms, M. Schömer, F. Wurm, M. I. Hermanns, C. J. Kirkpatrick, H. Frey, Macromol. Rapid Commun. 2010, 31, 1811-1815.

159.

"Synthesis, Characterization and Preliminary Biological Evaluation of P(HPMA)-b-P(LLA) Copolymers: A New Type of Functional Biocompatible Block Copolymer"
M. Barz, F. K. Wolf, F. Canal, K. Koynov, M. J. Vicent, H. Frey, R. Zentel, Macro­mol. Rapid Commun. 2010, 31, 1492-1500.

158.

"Amino Functional Poly(ethylene glycol) Copolymers via Protected Amino Glycidol"
B. Obermeier, F. Wurm, H. Frey, Macromolecules 2010, 43, 2244-2251.

157.

"Hyperbranched Polyglycerol-Based Lipids via Oxyanionic Polymerization: Toward Multifunctional Stealth Liposomes"
A. M. Hofmann, F. Wurm, E. Hühn, T. Nawroth, P. Langguth, H. Frey, Biomacromolecules 2010, 11, 568-574.

156.

"a,?n-Heterotelechelic Hyperbranched Polyethers Solubilize Carbon Nanotubes"
F. Wurm, A. M. Hofmann, A. Thomas, C. Dingels, H. Frey, Macromol. Chem. Phys 2010, 211, 932-939.

155.

"Hetero-Multifunctional Poly(ethylene glycol) Copolymers with Multiple Hydroxyl Groups and a Single Terminal Functionality "
C. Mangold; F. Wurm; B. Obermeier; H. Frey; Macromol. Rapid Commun. 2010, 31, 258-264.

154.

"Rapid Synthesis and MALDI-ToF Characterization of Poly(ethylene oxide) Multiarm Star Polymers."
M. Doycheva; E. Berger-Nicoletti; F. Wurm; H. Frey; Macromol. Chem. Phys. 2010, 211(1), 35-44.

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2009

153.

"Ionic Liquids on Demand in Continuous Flow."
D. Wilms; J. Klos; A.F.M. Kilbinger; H. Löwe; H. Frey; Org. Process Res. Dev. 2009, 13, 961-964.

152.

"Inimer-Promoted Synthesis of Branched and Hyperbranched Polylactide Copolymers"
F.K. Wolf; H. Frey; Macromolecules 2009, 42, 9443-9456.

151.

"Branched Versus Linear Polyisoprene: Flory-Huggins Interaction Parameters for their Solutions in Cyclohexane."
J. Eckelt; F. Samadi; F. Wurm; H. Frey; B. A. Wolf; Macromol. Chem. Phys. 2009, 210, 1433-1439.

150.

"Electroactive Linear-Hyperbranched Block Copolymers based on Linear Poly(ferrocenylsilane)s and Hyperbranched Poly(carbosilane)s"
F. Wurm, S. Hilf, H. Frey, Chem. Eur. J. 2009, 15, 9068-9077.

149.

"Ferrocenyl-Functionalized Long Chain Branched Polydienes"
F. Wurm, F. J. López-Villanueva, H. Frey, J. Polym. Sci. Pol. Chem. 2009, 47, 2518-2529.

148.

"Synthesis and Noncovalent Protein Conjugation of Linear-Hyperbranched PEG-Poly(glycerol) a,?n-Telechelics"
F. Wurm, J. Klos, H. J. Räder, H. Frey, J. Am. Chem. Soc. 2009,131, 7954-7955.

147.

"Poly(lactide)-block-poly(HEMA) block copolymers: an orthogonal one-pot combi­nation of ROP and ATRP, using a bifunctional initiator."
F. Wolf ; N. Friedemann; H. Frey; Macromolecules 2009, 42, 5622-5628.

146.

"Hyperbranched-Linear-Hyperbranched ABA-Type Block Copolymers based on Poly(ethylene oxide) and Poly(glycerol)"
F. Wurm, U. Kemmer-Jonas, H. Frey, Polym. Int. 2009, 58, 989-995.

145.

"Hyperbranched Polyglycerols with Elevated Molecular Weights: A Facile Two-Step Synthesis Protocol Based on Polyglycerol Macroinitiators"
D. Wilms, F. Wurm, J. Nieberle, P. Böhm, U. Kemmer-Jonas, H. Frey Macromolecules 2009, 42, 3230-3236.

144.

"Photocatalytic Printing of Inorganic Nanopatterns via Poly(styrene-block-carbosilane) Copolymer Thin Films on Titania Substrates"
J. Peng, A. Garcia Marcos, H. Frey, D. H. Kim, Chem. Commun., 2009, 1091-1093.

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2008

143.

"Amphiphilic Linear-Hyperbranched Block Copolymers with Linear Poly(ethylene oxide) and Hyperbranched Poly(carbosilane) Block"
F. Wurm, H. Schüle, H. Frey, Macromolecules 2008, 41, 9602-9611.

142.

"Electrochemical and bioelectrocatalytical properties of novel block-copolymers containing interacting ferrocenyl units"
M. P. García Armada, J. Losada, F. J. López-Villanueva, H. Frey, B. Alonso, C. M. Casado, J. Organomet. Chem. 2008, 693, 2803-2811.

141.

"Photocatalysis within a Hyperbranched Polyether with Benzophenone Core"
L. Pastor-Pérez, E. Barriau, H. Frey, J Pérez-Prieto, S.-E. Stiriba, J. Org. Chem. 2008, 73, 4680-4683.

140.

"Carbanions on Tap - Living Anionic Polymerization in a Microstructured Reactor"
F. Wurm, D. Wilms, J. Klos, H. Löwe and H. Frey, Macromol. Chem. Phys. 2008, 209 (11), 1106-1114.

139.

"Thermosensitive Hyperbranched Polyelectrolyte-Coated Gold Nanoparticles: Towards Smart Temperature- and pH-Nanosensors"
Y. Shen, M. Kuang, Z. Shen, J. Nieberle, H. Duan, H. Frey, Angew. Chem. Int. Ed. 2008, 47, 2227-2230.

138.

"Irregularly Branched and Functionalized Polybutadienes by a Facile Two-step Synthesis"
F. Wurm, F-J. Lopez-Villanueva, H. Frey, Macromol. Chem. Phys. 2008, 209, 675-684.

137.

"Synthesis and Characterization of Poly(glyceryl glycerol) Block Copolymers"
F. Wurm, J. Nieberle, H. Frey, Macromolecules 2008, 41(6), 1909-1911.

136.

"Double-Hydrophilic Linear-Hyperbranched Block Copolymers Based on Poly(ethylene oxide) and Poly(glycerol)"
F. Wurm, J. Nieberle, H. Frey, Macromolecules 2008, 41(4), 1184-1188.

135.

"Incorporation of a Photosensitizer-Core Within Hyperbranched Polyether Polyols: Effect of the Branched Shell on the Core Properties"
L. Pastor-Pérez, E.Barriau, E. Berger-Nicoletti, A.F.M.Kilbinger, J. Pérez-Prieto, H. Frey and S.-E. Stiriba, Macromolecules 2008, 41(4), 1189-1195.

134.

"Systematic Investigation of Functional Core Variation within Hyperbranched Polyglycerols"
E.Barriau, L. Pastor-Pérez, E. Berger-Nicoletti, A.F.M.Kilbinger, J. Pérez-Prieto, H. Frey and S.-E. Stiriba, J. Polym. Sci., Polym. Chem. 2008, 46(6), 2049-2061.

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2007

133.

"A Facile Two-Step Route to Branched Polyisoprenes via ABn-Macromonomers"
F.-J. Lopez-Villanueva, F. Wurm, A.F.M. Kilbinger, H. Frey, Macromol. Rapid Commun. 2007, 28(6), 704-709.

132.

"Synthesis of Hyperbranched Polyglycerol in a Continuous Flow Microreactor"
D. Wilms, J. Nieberle, J. Klos, H. Löwe, H. Frey, Chem. Eng. Technol. 2007, 30(11), 1519-1524.

131.

"Multi-Arm Star Poly(L-lactide) with Hyperbranched Polyglycerol Core"
C. Gottschalk, F. Wolf, H. Frey, Macromol. Chem. Phys. 2007, 208(15), 1657-1665.

130.

"Multiarm star polyglycerol-block-poly(HEMA) as a versatile precursor for the preparation of micellar nanocapsules with different properties."
H. Liu, Y. Chen, Z. Shen, H. Frey, Reactive & Functional Polymers 2007, 67(2), 156-164.

129.

"Novel Multifunctional Hyperbranched Polymeric Photoinitiators with Built-In Amine Coinitiators for UV Curing"
Y. Chen, J. Loccufier, L. Vanmaele, H. Frey, J. Mater. Chem. 2007, 17(32), 3389-3392.

128.

"Novel Multifunctional Polymeric Photoinitiators and Photo-coinitiators Derived from Hyperbranched Polyglycerol"
Y. Chen, J. Loccufier, L. Vanmaele, E. Barriau, H. Frey, Macromol. Chem. Phys. 2007, 208(15), 1694-1706.

127.

"Pencil Lead as a Matrix for MALDI-TOF Mass Spectrometry of Sensitive Functional Polymers"
E. Berger-Nicoletti, F. Wurm, A.F.M. Kilbinger, H. Frey, Macromolecules 2007, 40(3), 746-751.

126.

"Branched versus linear polyisoprene: Fractionation and phase behavior"
F. Samadi, J. Eckelt, B. A. Wolf, F-J. Lopez-Villanueva, H. Frey, Eur. Polym. J. 2007, 43, 4236-4243.

125.

"Water-Soluble Fluorescent Ag-Nanoclusters Obtained from Multi-Arm Star Poly(Acrylic Acid) as 'Molecular Hydrogel' Templates"
Z. Shen, H. Duan, H. Frey, Adv. Mater. 2007, 19, 349-352.

124.

"Water-soluble polyesters from long chain alkylesters of citric acid and poly(ethylene glycol)"
F. Barroso-Bujans, R. Martinez, M. Yazdani-Pedram, P. Ortiz, H. Frey, Eur. Polym. J. 2007, 43, 1288-1301.

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2006

123.

"Hybrid Organic-Inorganic Nanostructures Fabricated from Layer-by-Layer Self-Assembled Multilayers of Hyperbranched Polyglycerols and Phosphorus Dendrimers"
D.H. Kim, O.-J. Lee, E. Barriau, X. Li, A.-M. Caminade, J.-P. Majoral, H. Frey, W. Knoll, J. Nanosci. Nanotechnol. 2006, 6, 3871-3876.

122.

"Negatively charged hyperbranched polyether-based polyelectrolytes"
E. Barriau, H. Frey, A. Kiry, M. Stamm, F. Gröhn, Colloid Polym. Sci. 2006, 284 (11), 1293-1301.

121.

"Miscibility and properties of linear poly(L-lactide)/branched poly(L-lactide) copolyester blends"
M. Zuideveld, C. Gottschalk, H. Kropfinger, R. Thomann, M. Ursu, H. Frey, Polymer 2006, 47 (11), 3740-3746.

120.

"Hockey-puck micelles from oligo(p-benzamide)-b-PEG rod-coil block copolymers"
T.W. Schleuss, R. Abbel, M. Gross, D. Schollmeyer, H. Frey, M. Maskos, R. Berger, A.F.M. Kilbinger, Angew. Chem. Int. Ed. 2006, 45 (18), 2969-2975.

119.

"Optically active amphiphilic hyperbranched polyglycerols as templates for palladium nanoparticles"
Y. Chen, H. Frey, R. Thomann, S.-E. Stiriba, Inorg. Chim. Acta 2006, 359 (6), 1837-1844.

118.

"Properties of hyperbranched poly(E-caprolactone) copolyesters"
M. Ursu, I. Neuner, R. Thomann, M. Rusu, H. Frey, Materiale Plastice 2006, 43(3), 241-249.

117.

"Complex of Hyperbranched Polyethylenimine with Cuprous Halide as Recoverable Homogeneous Catalyst for the Atom Transfer Radical Polymerization of Methyl Methacrylate"
Z. Shen, Y. Chen, H. Frey, S.-E. Stiriba, Macromolecules 2006, 39 (6), 2092-2099.

116.

"Hyperbranched Polylactide Copolymers"
C. Gottschalk, H. Frey, Macromolecules 2006, 39 (5), 1719-1723.

115.

"Linear-Hyperbranched Block Copolymers Consisting of Polystyrene and Dendritic Poly(carbosilane) Block"
A. García Marcos, T. M. Pusel, R. Thomann, T. Pakula, L. Okrasa, S. Geppert, W. Gronski, H. Frey, Macromolecules 2006, 39 (3), 971-977.

114.

"Multi-Arm Star Polyglycerol-b-Poly(tert-butyl acrylate) and the Respective Multi-Arm Poly(acrylic acid) Stars"
Z. Shen, Y. Chen, E. Barriau, H. Frey, Macromol. Chem. Phys. 2006, 207 (1), 57-64.

113.

"Supramolecular Thermotropic Liquid Crystalline Materials with Nematic Mesophase Based on Methylated Hyperbranched Polyethylenimine and Mesogenic Carboxylic Acid"
Y. Chen, Z. Shen, L. Gehringer, H. Frey, S.-E. Stiriba, Macromol. Rapid Commun. 2006, 27 (1), 69-75

112.

"Synthesis of Multi-Arm Star Polymer Poly(glycerol)-block-poly(2-hydroxyethylmeth­acrylate)"
Y. Chen, Z. Shen, E. Barriau, H. Frey, Biomacromolecules 2006, 7 (3), 919-926.

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2005

111.

"Aliphatic Hyperbranched Copolyesters by Combination of ROP and AB2-Polycondensation"
M. Smet, C. Gottschalk, S. Skaria, H. Frey, Macromol. Chem. Phys. 2005, 206, 2421-2428.

110.

"Controlled Crystallization of CaCO3 on Hyperbranched Polyglyerol Adsorbed to Self-Assembled Monolayers"
M. Balz, E. Barriau, V. Istratov, H. Frey, W. Tremel, Langmuir 2005, 21, 3987-3991.

109.

"Linear-Hyperbranched Amphiphilic AB-Diblock Copolymers Based on Polystyrene and Hyperbranched Polyglycerol"
E. Barriau, A. García Marcos, H. Kautz, H. Frey, Macromol. Rapid Commun. 2005, 26 (11), 862-867.

108.

"Relationship between the Structure of Amphiphilic Copolymers and Their Ability To Disturb Lipid Bilayers"
T. Demina, I. Grozdova, O. Krylova, A. Zhirnov, V. Istratov, H. Frey, H. Kautz, N. Melik-Nubarov, Biochemistry 2005, 44, 4042-4054.

107.

"Rod-length dependent aggregation in a series of oligo(p-benzamide)-block- poly(ethy-lene glycol) rod-coil copolymers"
R. Abbel, T.W. Schleuss, H. Frey, A.F.M. Kilbinger, Macromol. Chem. Phys. 2005, 206 (20), 2067-2074.

106.

"Role of Topology and Amphiphilicity for Guest Encapsulation in Functionalized Hyperbranched Poly(ethylenimine)s"
Y. Chen, Z. Shen, L. Pastor-Perez, H. Frey, S.-E. Stiriba, Macromolecules 2005, 38 (2), 227-229.

105.

"Soluble oligoaramide precursors - A novel class of building blocks for rod-coil architec­tures"
R. Abbel, H. Frey, D. Schollmeyer, A.F.M. Kilbinger, Chem. Eur. J. 2005, 11 (7), 2170-2176.

104.

"Synergistic assembly of hyperbranched polyethylenimine and fatty acids leading to unusual supramolecular nanocapsules"
Y. Chen, Z. Shen, H.Frey, J. Pérez-Prieto, S.-E. Stiriba, Chem. Comm. 2005, 6, 755-757.

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2004

103.

"Electron-transfer reduction of selected alcohols with alkalide K-, K+(15-crown-5)2 via organometallic intermediates"
Z. Grobelny, A. Stolarzewicz, A. Maercker, S. Krompiec, J. Kasperczyk, J. Rzepa, H. Frey, J. Organomet. Chem. 2004, 689 (14), 2361-2367.

102.

"Hyperbranched Polymers: Structure of hyperbranched polyglycerol and amphiphilic poly-(glycerol ester)s in dilute aqueous and nonaqueous solution"
V. M. Garamus, T. V. Maksimova, H. Kautz, E. Barriau, H. Frey, U. Schlotterbeck, S. Mecking, W. Richtering, Macromolecules 2004, 37 (22), 8394-8399.

101.

"Non-linear effect of 18-crown-6 in propylene oxide polymerization with potassium glycidoxide used as the inimer"
A. Stolarzewicz, B. Morejko-Buz, Z. Grobelny, W. Pisarski, H. Frey, Polymer 2004, 45 (21), 7047-7051.

100.

"Optically active hyperbranched polyglycerol as scaffold for covalent and noncovalent immobilization of Platinum(II) NCN-pincer complexes. Catalytic application and recovery"
M.Q. Slagt, S.-E. Stiriba, H. Kautz, R. J.M. Klein Gebbink, H. Frey, G. van Koten, Organometallics 2004, 23 (7), 1525-1532.

99.

"Reactive core/shell type hyperbranched blockcopolyethers as new liquid rubbers for epoxy toughening"
J. Fröhlich, H. Kautz , R. Thomann, H. Frey, R. Mülhaupt, Polymer 2004, 45 (7), 2155-2164.

98.

"Synthesis and supramolecular association of immobilized NCN-pincer Platinum(II) complexes on hyperbranched polyglycerol supports"
S.-E. Stiriba, M.Q. Slagt, H. Kautz, R. J.M. Klein Gebbink, R. Thomann, H. Frey, G. van Koten, Chem. Eur. J. 2004, 10 (5), 1267-1273.

97.

"Synthesis of reactive hyperbranched and star-like polyethers and their use for toughening of vinylester-urethane hybrid resins"
J. Karger-Kocsis, J. Fröhlich, O. Gryshchuk, H. Kautz, H. Frey, R. Mülhaupt, Polymer 2004, 45 (4), 1185-1195.

96.

"Thermal properties and crystallization behavior of hyperbranched poly(e-caprolacton) copolyesters"
M. Ursu, H. Frey, I. Neuner, R. Thomann, M. Rusu, Romanian Reports in Physics 2004, 56 (3), 495-502.

95.

"Vapor-liquid equilibria of dendrimer and hyperbranched polymer solutions: Experimental data and modeling using UNIFAC-FV"
M. Seiler, J. Rolkera, L. Mokrushinab, H. Kautz, H. Frey, W. Arlt, Fluid Phase Equilibria 2004, 221, 83-96.

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2003

94.

"Form fluctuations of carbosilane dendrimers in dilute solution: a study using neutron spin echo spectroscopy "
B. Stark, C. Lach, B. Farago, H. Frey, C. Schlenk, B. Stühn, Colloid Polym. Sci. 2003, 281, 593.

93.

"Linear-dendritic nonionic poly(propylene oxide)-polyglycerol surfactants"
V. Istratov, H. Kautz, Y.-K. Kim, R. Schubert, H. Frey, Tetrahedron 2003, 59, 4017.

92.

"Phase behavior of n-alkyl-substituted polysilanes"
C. Müller, C. Peter, H. Frey, C. Schmidt, Silicon Chemistry 2003, 159-170.

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2002

91.

"Carboxylated and sulfonated poly(arylene-co -arylene sulfone)s: Thermostable polyelectrolytes for fuel cell applications"
D. Poppe, H. Frey, K.D. Kreuer, A. Heinzel, R. Mülhaupt, Macromolecules, 2002, 35, 7936.

90.

"Encapsulation of hydrophilic pincer-Platinum(II) complexes in amphiphilic hyperbranched polyglycerol nanocapsules"
M. Q. Slagt, S.-E. Stiriba, R. J. M. Klein Gebbink, H. Kautz, H. Frey, G. van Koten, Macromolecules 2002, 35, 5734.

89.

"Enzyme-catalyzed synthesis of hyperbranched aliphatic polyesters"
S. Skaria, M. Smet, H. Frey, Macromol. Rapid. Commun. 2002, 23, 292.

88.

"Hyperbranched molecular nanocapsules: Comparison of the hyperbranched architecture with the perfect linear analogue"
S.-E. Stiriba, H. Kautz, H. Frey, J. Am. Chem. Soc. 2002, 124, 9698.

87.

"Vapor-liquid and liquid-liquid equilibria of binary and ternary hyperbranched polyglycerol solutions"
M. Seiler, W. Arlt, G. Sadowski, H. Kautz, H. Frey, Fluid Phase Equilibria 2002, 5045, 1-21.

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2001

86.

"Acrylate-terminated macromonomers by Michael addition"
E. Müh, H. Weickmann, J. E. Klee, H. Frey, R. Mülhaupt, Macromol. Chem. Phys. 2001, 202, 3484.

85.

"Bismethacrylate-based hybrid monomers via Michael-addition reactions"
E. Müh, J. Marquardt, J. E. Klee, H. Frey, R. Mülhaupt, Macromolecules 2001, 34, 5778.

84.

"Control of the molecular weight of hyperbranched polyglycerols"
H. Kautz, A. Sunder, H. Frey, Macromol. Symp. 2001, 163 67.

83.

"Hyperbranched polyesters and their application in dental composites: monomers for low shrinking composites"
J. E. Klee, C. Schneider, D. Hölter, A. Burgath, H. Frey, R. Mülhaupt, Polymers for Advanced Technologies 2001, 12, 346.

82.

"Organic-inorganic hybrid nanocomposites prepared by means of sol-gel condensation of bismethacrylate silanes in reactive diluents"
E. Müh, H. Frey, J. E. Klee, R. Mülhaupt, Adv. Funct. Mater. 2001, 11, 425.

81.

"Organic-inorganic hybrid networks by the sol-gel process and subsequent photopolymerization"
E. Müh, M. Stieger, J. E. Klee, H. Frey, R. Mülhaupt, Journal of Polymer Science, Part A: Polymer Chemistry 2001, 39, 4274.

80.

"Synthesis of hyperbranched aromatic homo- and copolyesters via the slow monomer addition method"
A. Möck, A. Burgath, R. Hanselmann, H. Frey, Macromolecules 2001, 34, 7692.

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2000

79.

"An approach to core-shell-type architectures in hyperbranched polyglycerols by selective chemical differentiation"
R. Haag, J.-F. Stumbe, A. Sunder, H. Frey, A. Hebel, Macromolecules 2000, 33, 8158.

78.

"Chiral hyperbranched dendron analogues"
A. Sunder, R. Mülhaupt, R. Haag, H. Frey, Macromolecules 2000, 33, 253.

77.

"Copolymers of glycidol and glycidyl Ethers: Design of branched polyether polyols by combination of latent cyclic AB2 and ABR monomers"
A. Sunder, H. Türk, R. Haag, H. Frey, Macromolecules 2000, 33, 7682.

76.

"Dendrimers: Relationship between structure and biocompatibility in vitro, and prelimi-nary studies on the biodistribution of 125I-labeled polyamidoamine dendrimers in vivo"
N. Malik, R. Wiwattanapatapee, R. Klopsch, K. Lorenz, H. Frey, J. W. Weener, E. W. Meijer, W. Paulus, R. Duncan, Journal of Controlled Release 2000, 65, 133.

75.

"Functional poly(ethylene oxide) multiarm star polymers: Core-first synthesis using hyperbranched polyglycerol initiators"
R. Knischka, P. J. Lutz, A. Sunder, R. Mülhaupt, H. Frey, Macromolecules 2000, 33, 315.

74.

"Hyperbranched polyether polyols. A modular approach to complex polymer architectures"
A. Sunder, R. Mülhaupt, R. Haag, H. Frey, Adv. Mater. 2000, 12, 235.

73.

"Hyperbranched polyether-polyols based on polyglycerol: Polarity design by block copolymerization with propylene oxide"
A. Sunder, R. Mülhaupt, H. Frey, Macromolecules 2000, 33, 309.

72.

"Multi-arm star block copolymers based on e-caprolactone with hyperbranched polyglycerol core"
A. Burgath, A. Sunder, I. Th. Neuner, R. Mülhaupt, H. Frey, Macromol. Chem. Phys. 2000, 201, 792.

71.

"Preparation of catalytically active palladium nanoclusters in compartments of amphiphilic hyperbranched polyglycerols"
S. Mecking, R. Thomann, H. Frey, A. Sunder, Macromolecules 2000, 33, 3958.

70.

"Role of cyclization in the synthesis of hyperbranched aliphatic polyesters"
A. Burgath, A. Sunder, H. Frey, Macromol. Chem. Phys. 2000, 201, 782.

69.

"Synthesis and thermal behavior of esterified aliphatic hyperbranched polyether polyols"
A. Sunder, T. Bauer, R. Mülhaupt, H. Frey, Macromolecules 2000, 33, 1330.

68.

"Synthesis of poly(glycerol)-block-poly(methyl acrylate) multi-arm star polymers"
S. Maier, A. Sunder, H. Frey, R. Mülhaupt, Macromol. Rapid. Commun. 2000, 21, 226.

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1999

67.

"A novel phenol for use in convergent and divergent dendrimer synthesis: access to core functionalizable trifurcate carbosilane dendrimers-the X-ray crystal structure of [1,3,5-tris{4-(triallylsilyl)phenyl ester}benzene]"
R. A. Gossage, E. Munoz-Martinez, H. Frey, A. Burgath, M. Lutz, A. L. Spek, G. Van Koten, Chemistry-A European Journal 1999, 5, 2191.

66.

"Controlled synthesis of hyperbranched polyglycerols by ring-opening multibranching polymerization"
A. Sunder, R. Hanselmann, H. Frey, R. Mülhaupt, Macromolecules 1999, 32, 4240.

65.

"Degree of branching in hyperbranched polymers: Copolymerization of ABm monomers with AB and ABn monomers"
H. Frey, D. Hölter, Acta Polymer. 1999, 50, 67.

64.

"Dielectric relaxation in carbosilane dendrimers with cyanobiphenyl end groups"
B. Trahasch, H. Frey, K. Lorenz, B. Stühn, Colloid Polym. Sci. 1999, 277, 1186.

63.

"Dielectric relaxation in carbosilane dendrimers with perfluorinated end groups"
B. Trahasch, B. Stühn, H. Frey, K. Lorenz, Macromolecules 1999, 32, 1962.

62.

"Hyperbranched polyether polyols with liquid crystalline properties"
A. Sunder, M.-F. Quincy, R. Mülhaupt, H. Frey, Angewandte Chemie, International Edition 1999, 38, 2928.

61.

"Molecular nanocapsules based on amphiphilic hyperbranched polyglycerols"
A. Sunder, M. Kramer, R. Hanselmann, R. Mülhaupt, H. Frey, Angewandte Chemie, International Edition 1999, 38, 3552.

60.

"Phase behavior of poly(di-n-decylsilane)"
C. Müller, H. Frey, C. Schmidt, Monatshefte fuer Chemie 1999, 130, 175.

59.

"Silsesquioxane-based amphiphiles"
R. Knischka, F. Dietsche, R. Hanselmann, H. Frey, R. Mülhaupt, P. J. Lutz, Langmuir 1999, 15, 4752.

58.

"Styrene-vinylferrocene random and block copolymers by TEMPO-mediated radical polymerization"
M. Baumert, J. Fröhlich, M. Stieger, H. Frey, R. Mülhaupt, H. Plenio, Macromol. Rapid. Commun. 1999, 20, 203.

57.

"The superstructure of carbosilane dendrimers with perfluorinated end groups in bulk and in solution"
B. Stark, C. Lach, H. Frey, B. Stühn, Macromol. Symp. 1999, 146, 33.

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1998

56.

"Ambient-temperature liquid-crystalline bismethacrylates based on cholesterol. Cholesteric and smectic thermosets"
D. Hölter, H. Frey, R. Mülhaupt, J. E. Klee, Adv. Mater. 1998, 10, 864.

55.

"Branched macromonomers and their application in dental composites. Monomers for low-shrinking composites"
J. E. Klee, U. Walz, D. Hölter, H. Frey, R. Mülhaupt, Angew. Makromol. Chem. 1998, 260, 71.

54.

"Enhancing the Degree of Branching of Hyperbranched Polymers by Postsynthetic Modification"
C. Lach, H. Frey, Macromolecules 1998, 31, 2381.

53.

"Hyperbranched Carbosilane-Macromonomers: Polymerization and Coupling to a Core"
C. Lach, R. Hanselmann, H. Frey, R. Mülhaupt, Macromol. Rapid Commun., 1998, 19, 461.

52.

"Hyperbranched Polymers Prepared via the Core-Dilution/Slow Addition Technique: Computer Simulation of Molecular Weight Distribution and Degree of Branching"
R. Hanselmann, D. Hölter, H. Frey, Macromolecules 1998, 31, 3790.

51.

"Living anionic ring-opening polymerization of 1,1-dipropylsilacyclobutane"
R. Knischka, H. Frey, U. Rapp, F. J. Mayer-Posner, Macromol. Rapid. Commun. 1998, 19, 455.

50.

"Polymerization of polymer/ferroelectric liquid crystal composites formed with branched liquid crystalline bismethacrylates"
C. A. Guymon, R. Shao, D. Hölter, H. Frey, N. A. Clark, C. N. Bowman, Liquid Crystals 1998, 24, 263.

49.

"Segmental Dynamics in Dendrimers with Perfluorinated End Groups: A Study Using Quasielastic Neutron Scattering"
B. Stark, B. Stühn, H. Frey, C. Lach, K. Lorenz, B. Frick, Macromolecules 1998, 31, 5415.

48.

"Synthesis and properties of poly(dimethyldiphenylsilylenemethylene)"
F. Koopmann, H. Frey, Macromol. Chem. Phys. 1998, 199, 2119.

47.

"Thermodynamics of polymer blends of poly(isobutylene) and poly(dimethylsilylene­methylene)"
R. D. Maier, M. Kopf, D. Maeder, F. Koopmann, H. Frey, J. Kressler, Acta Polym. 1998, 49, 356.

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1997

46.

"Carbosilane dendrimers with perfluoroalkyl end groups: Core-shell macromolecules with generation-dependent order"
K. Lorenz, H. Frey, B. Stühn, R. Mülhaupt, Macromolecules 1997, 30, 6860.

45.

"Degree of branching (DB) in hyperbranched polymers. Enhancement of the DB: Scope and limitations"
D. Hölter, H. Frey, Acta Polym. 1997, 48, 298.

44.

"Degree of branching in hyperbranched polymers"
D. Hölter, A. Burgath, H. Frey, Acta Polym. 1997, 48, 30.

43.

"Ethene and propene copolymers containing silsesquioxane side groups"
A. Tsuchida, C. Bolln, F. G. Sernetz, H. Frey, R. Mülhaupt, Macromolecules 1997, 30, 2818.

42.

"Hyperbranched polycarbosilane macromonomers bearing oxazoline functionalities"
C. Lach, P. Müller, H. Frey, R. Mülhaupt, Macromol. Rapid Commun. 1997, 18, 253.

41.

"Molecular force field study concerning the host properties of carbosilane dendrimers"
C. Lach, D. Brizzolara, H. Frey, Macromol. Theory Simul. 1997, 6, 371.

40.

"Organopalladium-functionalized dendrimers: Insertion of Palladium(0) into peripheral Carbon-Iodine bonds of carbosilane dendrimers derived from polyols: Crystal structure of Si{(CH2)3O2CC6H4I-4}4"
J. L. Hoare, K. Lorenz, N. J. Hovestad, W. J. J. Smeets, A. L. Spek, A. J. Canty, H. Frey, G. van Koten, Organometallics 1997, 16, 4167.

39.

"Progress in controlled polymerization and design of novel polymer architectures"
M. Baumert, H. Frey, M. Holderle, J. Kressler, F. G. Sernetz, R. Mülhaupt, Macromol. Symp 1997, 121, 53.

38.

"Thermal properties of the homologous series of 8-fold alkyl-substituted octasilses­quioxanes"
C. Bolln, A. Tsuchida, H. Frey, R. Mülhaupt, Chem. Mater. 1997, 9, 1475.

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1996

37.

"A mesogen-functionalized carbosilane dendrimer. A dendritic liquid crystalline polymer"
K. Lorenz, D. Hölter, B. Stühn, R. Mülhaupt, H. Frey, Adv. Mater. 1996, 8(5), 414.

36.

"Characterization of supra-molecular assemblies of N-(n-alkyl)-N'-D-maltosylsemi­carbazone adsorbates by atomic force microscopy"
K. Craemer, S. Demharter, R. Mül­haupt, H. Frey, S. N. Magonov, I. Tuzov, M. H. Whangbo, New J. Chem. 1996, 20, 5.

35.

"Charge carrier mobilities in substituted polysilylenes: Influence of backbone conformation"
G. P. van der Laan, M. P. de Haas, A. Hummel, H. Frey, M. Möller, J. Phys. Chem. 1996, 100, 5470.

34.

"Dendritic polyols based on carbosilanes - lipophilic dendrimers with hydrophilic skin"
H. Frey, K. Lorenz, R. Mülhaupt, Macromol. Symp. 1996, 102, 19.

33.

"Liquid crystalline thermosets based on branched bismethacrylates"
D. Hölter, H. Frey, R. Mülhaupt, J. E. Klee, D. D. Trey, Macromolecules 1996, 29, 7003.

32.

"Miscibility of poly(sila-a-methylstyrene) with polystyrene"
R.-D. Maier, J. Kressler, B. Rudolf, P. Reichart, F. Koopmann, H. Frey, R. Mülhaupt, Macromolecules 1996, 29, 1490.

31.

"Mono- and multilayers of mesogen-substituted carbosilane dendrimers on mica"
M. C. Coen, K. Lorenz, J. Kressler, H. Frey, R. Mülhaupt, Macromolecules 1996, 29, 8069.

30.

"Optical and charge transport properties of di-n-hexyl substituted polysilylene and polygermylene"
G. P. van der Laan, M. P. de Haas, C. A. van Walree, J. van Slageren, L. W. Jenneskens, H. Frey, Macromol. Symp. 1996, 102, 355.

29.

"Poly(methylphenylsilylenemethylene): The carbosilane analog of poly(a-methyl-styrene)"
F. Koopmann, A. Burgath, R. Knischka, J. Leukel, H. Frey, Acta Polym. 1996, 47, 377.

28.

"Solid state NMR investigation of C1-deuterated poly(di-n-hexylsilylene)"
C. Müller, C. Schmidt, H. Frey, Macromolecules 1996, 29, 3320.

27.

"Substrate-induced orientation of poly(di-n-alkylsilylenes)"
S. Sheiko, B. Blommers, H. Frey, M. Möller, Langmuir 1996, 12, 584.

26.

"Synthesis and photoinitiated cationic polymerization of 2-methylene-7-phenyl-1,4,6,9-tetraoxaspiro[4.4]nonane"
C. Bolln, H. Frey, R. Mülhaupt, Macromolecules 1996, 29, 3111.

25.

"Synthesis of poly(silylenemethylene)s symmetrically substituted with alkyl side groups containing 4-6 carbon atoms"
F. Koopmann, H. Frey, Macromolecules 1996, 29, 3701.

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1995

24.

"Carbosilane-based dendritic polyols"
K. Lorenz, R. Mülhaupt, H. Frey, U. Rapp, F. J. Mayer-Posner, Macromolecules 1995, 28, 6657.

23.

"Charge carrier mobilities in liquid crystalline mesomorphic poly(di-n-alkylsilylene)s: influence of backbone conformation"
G. P. van der Laan, M. P. de Haas, H. Frey, M. Möller, Macromol. Symp. 1995, 96, 219.

22.

"Crystalline and disordered state of poly(dihexylsilylene) copolymers"
H. Frey, M. Möller, K. Matyjaszewski, D. Olefin, Macromol. Chem. Phys. 1995, 196, 1181.

21.

"Fullerene-end-capped polystyrenes: Monosubstituted polymeric C60-derivatives"
C. Weis, C. Friedrich, R. Mülhaupt, H. Frey, Macromolecules 1995, 28, 403.

20.

"Hydrosilylation of 1-alkenes with dichlorosilane"
G. J. J. Out, H.-A. Klok, L. Schweg­ler, H. Frey, M. Möller, Macromol. Chem. Phys. 1995, 196, 185.

19.

"Photoinitiated cationic polymerization of 2-phenyl-substituted 4-methylene-1,3-dioxolanes"
C. Bolln, H. Frey, R. Mülhaupt, J. Polym. Sci., Part A: Polym. Chem. 1995, 33, 587.

18.

"Polysilylenes with ethynylphenyl substituents"
H. Frey, E. J. Schulenburg, M. Möller, H. Noorlander-Bunt, J. F. J. Engbersen, D. N. Reinhoudt, Acta Polym. 1995, 46, 45.

17.

"Structure and chiroptical properties of bis[(S)-methylbutyl]silylene-dipentylsilylene copolymers"
H. Frey, M. Möller, A. Turetskii, B. Lotz, K. Matyjaszewski, Macromolecules 1995, 28, 5498.

16.

"Synthesis and gel formation of amphiphilic semicarbazones containing saccharide units"
S. Demharter, H. Frey, M. Drechsler, R. Mülhaupt, Colloid Polym. Sci. 1995, 273, 661.

15.

"Synthesis and mesomorphic behavior of poly(dipropylsilylenemethylene)"
F. Koopmann, H. Frey, Macromol. Rapid Commun. 1995, 16, 363.

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1994

14.

"Anisotropic Radiation-Induced Conductivity in Oriented Poly(di-n-hexylsilylene) in the Solid Phase and in the Mesophase"
G. P. van der Laan, M. P. de Haas, A. Hummel, H. Frey, S. Sheiko, M. Möller, Macromolecules 1994, 27, 1897.

13.

"Chiral Poly(dipentylsilylene) Copolymers"
H. Frey, M. Möller, K. Matyjaszewski, Macromolecules 1994, 27, 1814.

12.

"Mesomorphic flexible chain polymers based on silicon"
G. J. J. Out, S. Siffrin, H. Frey, D. Oelfin, G. Koegler, M. Möller, Polym. Adv. Technol. 1994, 5, 796.

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1993

11.

"Blending, gel drawing and UV photolysis of ultrahigh-molecular-weight polyethylene and poly(di-n-pentylsilylene)"
M. Möller, H. Frey, S. Sheiko, Colloid Polym. Sci. 1993, 271, 554.

10.

"Crystalline order and mesophases of poly(di-n-alkyl)silylene copolymers"
H. Frey, M. Möller, D. Oelfin, Vysokomol. Soedin., Ser. A Ser. B 1993, 35, 1755.

9.

"Highly mobile charge carriers in poly(di-n-alkyl)silanes in the solid and in the mesophase"
G. P. van der Laan, M. P. de Haas, J. M. Warman, H. Frey, M. Möller, Mol. Cryst. Liq. Cryst. Sci. Technol., Sect. A 1993, 236, 165.

8.

"Highly oriented poly(di-n-alkylsilylene) films on oriented PTFE substrates"
H. Frey, S. Sheiko, M. Möller, J. C. wittmann, B. Lotz, Adv. Mater. 1993, 5(12), 917.

7.

"Radiation-induced conductivity in poly(methylphenylsilylene) and poly(di-n-hexylsilylene) studied by time-resolved microwave conductivity"
H. Frey, M. Möller, M. P. De Haas, N. J. P. Zenden, P. G. Schouten, G. P. Van der Laan, J. M. Warman, Macromolecules 1993, 26, 89.

6.

"Synthesis and properties of poly[bis(g-ethoxypropyl)silylene]"
H. Frey, G. J. J. Out, M. Möller, D. Greszta, K. Matyjaszewski, Macromolecules 1993, 26, 6231.

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1992

5.

"FT-IR studies on the mechanical response of the crystalline fraction in ultrastrong polyethylene tapes"
S. Sheiko, H. Frey, M. Möller, Colloid Polym. Sci. 1992, 270, 440.

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1991

4.

"Crystallization and mesomorphic disordering of di-n-hexylsilylene/di-n-pentylsilylene copolymers"
H. Frey, K. Matyjaszewski, M. Möller, D. Oelfin, Colloid Polym. Sci. 1991, 269, 442.

3.

"Order and thermochromism of poly(di-n-alkyl)silane copolymers"
H. Frey, M. Möller, K. Matyjaszewski, Synth. Met. 1991, 42, 1571.

2.

"Synthesis and characterization of polysilanes"
K. Matyjaszewski, M. Cypryk, H. Frey, J. Hrkach, H. K. Kim, M. Möller, K. Ruehl, M. White, J. Macromol. Sci., Chem. 1991, A28, 1151.

1.

"Third-order nonlinear optical properties of polysilane films"
P. G. Kaatz, G. D. Patterson, H. K. Kim, H. Frey, K. Matyjaszewski, Mater. Res. Soc. Symp. Proc. 1991, 214, 17.

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II. Review Articles (Peer Reviewed)

R36

 "Hydroxamic Acid – An Underrated Moiety? Marrying Bioinorganic Chemistry and Polymer Science"
J. Keth, T. Johann and H. Frey, Biomacromolecules 2020. DOI: 10.1021/acs.biomac.0c00449.

R35

"Long-Chain Alkyl Epoxides and Glycidyl Ethers: An Underrated Class of Monomers"
P. Verkoyen and H. Frey, Macromol. Rapid Commun. 2020. DOI: 10.1002/marc.202000225.

R34

"Amino-functional polyethers: versatile, stimuli-responsive polymers"
P. Verkoyen and H. Frey, Polymer Chemistry 2020,11, 3940-3950. DOI: 10.1039/D0PY00466A.

R33

"Functional Polycarbonates from Carbon Dioxide and Tailored Epoxide Monomers: Degradable Materials and Their Application Potential"
M. Scharfenberg, J. Hilf, H. Frey, Adv. Funct. Mater. 2018, 28, 1704302. DOI: 10.1002/adfm.201704302.

R32

“Quicklebendig seit 60 Jahren: Die lebende anionische Polymerisation”
Daniel Leibig, Jan Morsbach, Eduard Grune, Jana Herzberger, Axel H.E. Müller, Holger Frey, Chem. Unserer Zeit 2017, 51, 254–263. DOI: 10.1002/ciuz.201700774.

R31

“Recent advances in the use of nanoparticles for allergen-specific immunotherapy“
Hannah Pohlit, Iris Bellinghausen, Holger Frey, Joachim Saloga, Allergy 2017, 72, 1461–1474. DOI: 10.1111/all.13199.

R30

"Polymerization of Ethylene Oxide, Propylene Oxide and Other Alkylene Oxides: Synthesis, Novel Polymer Architectures and Bioconjugation"
J. Herzberger, K. Niederer, H. Pohlit, J. Seiwert, M. Worm, F. R. Wurm, H. Frey, Chem. Rev. 2016, 116 (4), 2170-2243. DOI: 10.1021/acs.chemrev.5b00441.

R29

"Beyond Poly(ethylene glycol): Linear Polyglycerol as a Multifunctional Polyether for Biomedical and Pharmaceutical Applications"
A. Thomas, S. S. Müller, H. Frey, Biomacromolecules 2014, 15, 1935-1954. DOI: 10.1021/bm5002608.

R28

"Polyether-Based Lipids Synthesized with an Epoxide Construction Kit: Multivalent Architectures for Functional Liposomes"
S. S. Müller, C. Dingels, A. M. Hofmann, H. Frey, ”Tailored Polymer Architectures for Pharmaceutical and Biomedical Applications"€, ACS Books; Chapter 2 2013, 11-25. DOI: 10.1021/bk-2013-1135.ch002.

R27

”Grafting of Hyperbranched Polymers: From Unusual Complex Polymer Topologies to Multivalent Surface Functionalization"€
C. Schüll, H. Frey, Polymer 2013, 54, 5443-5455. DOI: 10.1016/j.polymer.2013.07.065.

R26

"From Biocompatible to Biodegradable: Poly(ethylene glycol)s with In-Chain Cleavable Linkages"
C. Dingels, H. Frey Adv. Polym. Sci. 2013, 262, 167-190. DOI: 10.1007/12_2013_235.

R25

"Aminofunctional Polyethers: Smart Materials For Applications in Solution and on Surfaces"
V. S. Wilms, H. Frey, Polym. Int. 2013, 62, 849-859. DOI: 10.1002/pi.4496.

R24

"Hyperbranched Aliphatic Polyether Polyols"
M. Schömer, C. Schüll, H. Frey J. Polym. Sci. A, Polym. Chem. 2013, 51, 995-1019. DOI: 10.1002/pola.26496.

R23

"Micro-Flow Technology in Polymer Synthesis"
C. Tonhauser, A. Natalello, H. Löwe, H. Frey, Macromolecules 2012, 45, 9551-9570 (Invited Perspectives-Article). DOI: 10.1021/ma301671x.

R22

"Functional PEG-based polymers with reactive groups via anionic ROP of tailor-made epoxides"
C. Mangold, F. Wurm, H. Frey, Polymer Chemistry 2012, 3 (7), 1714-1721. DOI: 10.1039/C2PY00489E.

R21

"Nonlinear Macromolecules by Ring-Opening Polymerization"
Schüll, C.; Wilms, D.; Frey, H.; In: Matyjaszewski, K. and Möller, M. (eds.) Polymer Science: A Comprehensive Reference, 2012, Vol. 4, pp. 571-596, Amsterdam: Elsevier BV. DOI: 10.1016/B978-0-444-53349-4.00118-7.

R20

" Hyperbranched Polymers: Synthetic Methodology, Properties, and Complex Polymer Architectures"
Wurm, F.; Frey, H.; In: Matyjaszewski, K. and Möller, M. (eds.), Polymer Science: A Comprehensive Reference, 2012, Vol. 6, pp. 177-198, Amsterdam: Elsevier BV. DOI: 10.1016/B978-0-444-53349-4.00163-1.

R19

"Von der Kosmetik zum Ionenleiter: Die vielen Gesichter des Poly(ethylenglykols)"
Chemie in unserer Zeit, C. Dingels, M. Schömer, H. Frey, 2011, 45, 338-349. DOI: 10.1002/ciuz.201100551.

R18

"Multifunctional Poly(ethylene glycol)s"
B. Obermeier, F. Wurm, C. Mangold, H. Frey, Angew. Chem. Int. Ed.2011, 50, 7988 - 7997. DOI: 10.1002/anie.201100027.

"Multifunktionelle Poly(ethylenglycole)"
B. Obermeier, F. Wurm, C. Mangold, H. Frey, Angew. Chem. 2011, 123, 8136 - 8146. DOI: 10.1002/ange.201100027.

R17

"Linear-Dendritic Block Copolymers: The State of the Art and Exciting Perspectives"
F. Wurm, H. Frey, Prog. Polym. Sci. 2011, 36, 1-52. DOI: 10.1016/j.progpolymsci.2010.07.009.

R16

"A Road Less Traveled to Functional Polymers: Epoxide Termination in Living Carb­anionic Polymer Synthesis"
C. Tonhauser, H. Frey, Macromol. Rapid Commun. 2010, 31, 1938-1947. DOI: 10.1002/marc.201000353.

R15

"Hyperbranched Polyglycerols: From the Controlled Synthesis of Biocompatible Polyether Polyols to Multipurpose Applications"
D. Wilms; S.-E. Stiriba; H. Frey; Accounts Chem. Res. 2010, 43 (1), 129-141. DOI: 10.1021/ar900158p.

R14

"Ionic Polymerizations in Microstructured Reactors"
D. Wilms, F. Wurm, J. Klos, H. Löwe, H. Frey, Chemistry Today (Chimica Oggi), 2008, 26, 63-69.

R13

"Microstructured Reactors for Polymer Synthesis: A Renaissance of Continuous Flow Processes for Tailor-Made Macromolecules?"
D. Wilms, J. Klos, H. Frey, Macromol. Chem. Phys. 2008, 209(4), 343-356. DOI: 10.1002/macp.200700588.

R12

"Dendritic polyglycerol: a new versatile biocompatible material"
H. Frey, R. Haag, Reviews in Molecular Biotechnology 2002, 90, 257. DOI: 10.1016/S1389-0352(01)00063-0.

R11

"Dendritic polymers in biomedical applications: From potential to clinical use in diagnostics and therapy"
S.-E. Stiriba, H. Frey, R. Haag, Angewandte Chemie, International Edition 2002, 41, 1329. DOI: 10.1002/1521-3773(20020415)41:8<1329::AID-ANIE1329>3.0.CO;2-P.

R10

"Hyperbranched polymers: from dendritic macromolecules to functional materials"
H. Frey, H. Kautz, Nachr. Chem. 2002, 50, 1218. DOI: 10.1021/acs.macromol.7b01843.

R9

H. Frey, R. Haag, Encyclopedia of Materials Science and Engineering, E. J. Kramer ed., Elsevier, 2001, 3997. DOI: 10.1021/acs.macromol.7b01843.

R8

"Controlling the growth of polymer trees: concepts and perspectives for hyperbranched polymers"
A. Sunder, J. Heinemann, H. Frey, Chemistry - A European Journal 2000, 6, 2499. DOI: 10.1021/acs.macromol.7b01843.

R7

"From random coil to extended nanocylinder: dendrimer fragments shape polymer chains"
H. Frey, Highlights in Org. Synth. IV; H. G. Schmalz, Ed., Wiley-VCH, Weinheim, New York, 2000, 306. DOI: 10.1021/acs.macromol.7b01843.

R6

"Silicon-based dendrimers"
H. Frey, C. Schlenk, Top. Curr. Chem. 2000, 210, 69. DOI: 10.1021/acs.macromol.7b01843.

R5

"Carbosilane dendrimers. Synthesis, functionalization, application"
C. Schlenk, H. Frey, Monatshefte fuer Chemie 1999, 130, 3. DOI: 10.1021/acs.macromol.7b01843.

R4

"Heteroatom-based dendrimers" H. Frey, C. Lach, K. Lorenz, Adv. Mater. 1998, 10, 279. DOI: 10.1021/acs.macromol.7b01843.

R3

"From random coil to extended nanocylinder: dendrimer fragments shape polymer chains"
H. Frey, Angewandte Chemie, International Edition 1998, 37, 2193. DOI: 10.1021/acs.macromol.7b01843.

R2

"Hyperbranched polymers. Macromolecular trees become popular"
A. Burgath, H. Frey, GIT Labor-Fachzeitschrift 1998, 42, 516. DOI: 10.1021/acs.macromol.7b01843.

R1

"Dendrimere: Von der Ästhetik zur Anwendung?"
H. Frey, K. Lorenz, C. Lach, Chem. Unserer Zeit 1996, 30, 75. DOI: 10.1021/acs.macromol.7b01843.

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III. Other Contributions / Non Refereed

W68

"Advanced Control over Glycidol Polymerization: Hyperbranched Polyglycerols via Macroinitiators"
D. Wilms, H. Frey, PMSE Prepr. 2009, 100, 120-121.

W67

"Aliphatic Linear-Hyperbranched Block-Copolymer Amphiphiles "
F. Wurm, H.Schüle and H. Frey, PMSE Prepr. 2009, 100, 298-299.

W66

"Linear-Hyperbranched Block Copolymers Containing Organometallic Blocks "
F.Wurm, I.Manners, H. Frey, PMSE Prepr. 2009 , 100, 408-409.

W65

"Linear-Hyperbranched Block Copolymers - A Progress Report "
F. Wurm, H. Frey, Polymer Prep. 2009, 50.

W64

”Baumartige Moleküle: Von Nanokapseln zur Biomedizin"€,
Forschungsmagazin Natur und Geist, 2009, 15-18.

W63

"Well-defined hyperbranched and linear polymers by anionic polymerization in continuous flow"
D. Wilms, J. Klos F. Wurm, H. Löwe, H. Frey, PMSE Prepr. 2008, 98, 642-643.

W62

"Tailoring the LCST of thermosensitive hyperbranched polyelectrolyte coated gold nanoparticles"
Y. Shen, M. Kuang, J. Nieberle, Z. Shen, H. Duan, H. Frey, Polymer Prepr. 2008, 49(1), 119-120.

W61

"Synthesis of hyperbranched polylactides by self condensing ring-opening branching polymerization"
F. Wolf, H. Frey, Polymer Prepr. 2008, 49(1), 109-110.

W60

"Nonlinear block copolymers based on poly(ethylene oxide) and branched poly(glycerol)s"
F. Wurm, J. Nieberle, H. Frey, Polymer Prepr. 2008, 49(1), 68-69.

W59

"Amphiphilic hyperbranched-hyperbranched block copolymers based on polycarbo­silane and polyglycerol."
H. Schüle, J. Nieberle, H. Frey, PMSE Prepr. 2007, 96, 252-253.

W58

"Azide end-capped hyperbranched polyglycerol: complex polymer structures via click chemistry."
Y. Shen, Z. Shen, J. Nieberle, E. Barriau, H. Frey, PMSE Prepr. 2007, 96, 603-604.

W57

"Synthesis of hyperbranched polyglycerol via ring-opening polymerization of glycidol in a microstructured reactor"
D. Wilms, J. Nieberle, J. Klos, H. Löwe, H. Frey, PMSE Prepr. 2007, 97, 101-102.

W56

"Synthesis of complex hyperbranched polymer amphiphiles."
J. Nieberle, F. Wurm, H. Frey, PMSE Prepr. 2007, 96, 359-360.

W55

"Highly branched polymers: recent innovations and exciting challenges."
H. Frey, Macromol. Chem. Phys. 2007, 208(15), 1613-1614.

W54

"Two-step route to hyperbranched polyisoprenes via ABn-macromonomers"
F.-J. Lopez-Villanueva, F. Wurm, A.F.M. Kilbinger, H. Frey, PMSE Prepr. 2006, 95, 20-21.

W53

"Synthesis and superstructures of novel linear and linear-hyperbranched amphiphilic block copolymers"
F.-J. Lopez-Villanueva, E. Barriau, T.W. Schleuss, R. Berger, A.F.M. Kilbinger, H. Frey, PMSE Prepr. 2006, 95, 780-781.

W52

"Influence of block length for ferrocenyl-functionalized block copolymers as precursor for biosensoric applications"
F.-J. Lopez-Villanueva, A. Garcia Marcos, K. Fischer, M. Schmidt, B. Alonso, C.M. Casado, M. Pilar Garcia Armada, J. Losada, H. Frey, Polymer Prepr. 2006, 47 (2), 1087-1088.

W51

"Branched multi-arm star poly(glycerol)-b-poly(acrylic acid) polyelectrolytes for biomineralization of CaCO3 at self-assembled monolayer surfaces."
H. Frey, Z. Shen, E. Barriau, N. Loges, M. Balz, W. Tremel, PMSE Prepr. 2006, 94, 146-147.

W50

"Macromolecular Chemistry 2005"
H. Frey, F. Gröhn, A. Kilbinger, Nachrichten aus der Chemie 2006, 54 (3), 292-300.

W49

"Covalent and non-covalent nanocapsules based on hyperbranched polyethylenimine (PEI)"
Z. Shen, Y. Chen, H. Frey, S.-E. Stiriba, Polymer Prepr. 2005, 46(1), 619-620.

W48

"Linear-hyperbranched amphiphilic block copolymers self-assembled into well-defined superstructures"
E. Barriau, A. García Marcos, K. Fischer, H. Kautz, M. Schmidt, H. Frey, Polymer Prepr. 2005, 46, 51.

W47

"Supramolecular organization of oligo-aramide rod-coil block-copolymers in solution"
R. Abbel, T. Schleuss, H. Frey, R. Berger, U. Rietzler, A.F.M. Kilbinger, Polymer Prepr. 2005, 46 (1), 90-91.

W46

"Controlled multibranching polymerization of hydroxy epoxides by slow monomer addition: A universal strategy for well-defined hyperbranched polyethers"
H. Kautz, E. Barriau, Y. Chen, M. P. Collado, R. Wissert, H. Frey, PMSE Prepr. 2003, 88, 549.

W45

"Enzyme-catalyzed synthesis of hyperbranched polyesters"
H. Frey, I. Th. Neuner, M. Ursu, Polym. Prepr. 2003, 44, 593.

W44

"Hyperbranched aliphatic copolyesters by branching ROP/polycondensation"
I. Th. Neuner, M. Ursu, S. Skaria, H. Frey, PMSE Prepr. 2003, 88, 342.

W43

"Linear-hyperbranched nonionic PPO-polyglycerol surfactants"
H. Kautz, V. Istratov, Y.-K. Kim, R. Schubert, H. Frey, Polymer Prepr. 2003, 44, 526.

W42

Buchrezension: "Dendrimers and other Dendritic Polymers By Jean M. J. Fréchet and Donald A. Tomalia" by J. M.J. Fréchet and D. A. Tomalia. John Wiley & Sons, New York 2001. H. Frey, Angew. Chem. Int. Ed. 2003, 42, 2215.

W41

"New approach to hyperbranched polylactide copolymers"
C. Gottschalk, H. Frey, PMSE Prepr. 2003, 88, 363.

W40

"Novel polymer-brush architectures: Linear-hyperbranched block copolymers"
A. Garcia Marcos, T. Pusel, B. de Juan de Castro, S. Geppert, R. Thomann, W. Gronski, H. Frey, Polymer Prepr. 2003, 44, 534.

W39

Buchrezension: "Dendrimers and Dendrons. Concepts, Syntheses, Applications" by G. R. Newkome, C. N. Moorefield, F. Vögtle, Wiley-VCH, Weinheim 2001,
H. Frey, Nachrichten aus der Chemie 2002.

W38

Buchrezension: "Design of Molecular Materials - Supramolecular Engineering" by J. Simon and P. Bassoul, Wiley and Sons, Chichester and New York, 2000.
H. Frey, Angewandte Chemie 2002, Angew. Chem. Int. Ed. 2002, 41, 660.

W37

Frey, H.; Haag, R.; „Hyperbranched Polymers in Industry"€, Encyclopedia of Materials Science and Engineering, E. J. Kramer ed., Elsevier, 2001, 3997.

W36

"Copolymerization of arylchlorides by nickel-catalyzed coupling: Novel polyelectrolytes"
D. Poppe, H. Frey, A. Heinzel, R. Mülhaupt, PMSE Prepr. 2001, 84, 333.

W35

"Hyperbranched LC-polymers based on polyglycerol scaffolds"
M.-F. Quincy, H. Kautz, H. Frey, PMSE Prepr. 2001, 84, 647.

W34

"Hyperbranched polyglycerol: elevated molecular weights and fractionation"
H. Kautz, R. Hanselmann, H. Frey, E. Schwab, S. Mecking, PMSE Prepr. 2001, 84, 943.

W33

"Linear polymers with hyperbranched side chains via the "hypergrafting" strategy: a simulation study and first synthetic results"
T. Pusel, H. Frey, Y. U. Lee, W. H. Jo, PMSE Prepr. 2001, 84, 730.

W32

"Perhalogenated and tosylated hyperbranched polyethers"
I. Th. Neuner, H. Kautz, H. Frey, PMSE Prepr. 2001, 84, 68.

W31

"Structured hydrogels based on poly(ethylene oxide) multi-arm stars with hyperbranched polyglycerol core"
R. Knischka, P. J. Lutz, A. Sunder, H. Frey, PMSE Prepr. 2001, 84, 945.

W30

"Copolymers of glycidol and allylglycidyl ether: Hyperbranched polymers with orthogonal end-groups"
A. Sunder, H. Türk, R. Haag, H. Frey, PMSE Prepr. 2000, 82, 15.

W29

"Bismethacrylate-based hybrid monomers for advanced dental composites"
E. Müh, J. E. Klee, H. Frey, R. Mülhaupt, PMSE Prepr., 2000, 82, 99.

W28

"Hyperbranched polycarbosilanes: A versatile class of inorganic polymers"
H. Frey, C. Lach, C. Schlenk, T. Pusel, Polymer Prepr. 2000, 41, 568.

W27

Buchrezension:"Synthesis of Polymers", Materials Science and Technology Series, A.-D. Schlüter, ed., Wiley-VCH, Weinheim, 1999.
H.Frey, Angew. Chem. 2000, 112, 998; Angew. Chem. Int. Ed. Engl. 2000, 39, 644.

W26

"A versatile route to hyperbranched polyglycerols and new branched polymer architectures"
A. Sunder, H. Frey, R. Mülhaupt, PMSE 1999, 80, 203.

W25

"Tailoring of hyperbranched polymers: copolymerization of ABm-monomers with AB monomers"
H. Frey, D. Hölter, PMSE Prepr. 1999, 80, 266.

W24

"Hyperbranched polyesters and copolyesters prepared via the slow addition method
A. Burgath, A. Möck, R. Hanselmann, H. Frey, PMSE Prepr. 1999, 80, 126.

W23

Buchrezension: "Heterogeneous Modification of Polymers: Matrix and Surface Reactions" by J. J.-Grodzinski, Wiley, New York 1997.
H. Frey Adv. Mater. 1999, 11, 178.

W22

"Starre Molekülscheibchen durch nichtkovalente Wechselwirkungen"

H. Frey, Chem. Unserer Zeit 1999, 33, 56.

W21

"Synthesis of hyperbranched aromatic copolyesters with controlled degree of branching"
A. Möck, A. Burgath, R. Hanselmann, H. Frey, PMSE Prepr. 1999, 80, 173.

W20

"Verzweigte Bismethacrylate - ein variables Baukastensystem für schwundarme Matrixsysteme"
J.E. Klee, D. Hölter, H. Frey, R. Mülhaupt, Werkstoffwoche 98, Band VIII, Wiley-VCH, Weinheim 1999, 181-186.

W19

"Nonionic silsesquioxane based amphiphiles"
R. Knischka, F. Dietsche, R. Mülhaupt, H. Frey, Book of Abstracts, 216th ACS National Meeting, 1998, COLL, 123.

W18

"Branched bismethacrylates - a variable modular system for low-shrinkage matrix system"
J. E. Klee, D. Hölter, H. Frey, R. Mülhaupt, Werkstoffwoche '98, Band VIII: Symposium 1998, 10, 181.

W17

"Branched bismethacrylates based on bis-GMA - a systematic route to low shrinkage composites"
D. Hölter, H. Frey, R. Mülhaupt, Polym. Prepr. 1997, 38(2), 84.

W16

"Computer simulation of molar mass distribution and degree of branching of hyperbranched polymers synthesized via core-dilution/slow addition"
R. Hanselmann, D. Hölter, H. Frey, PMSE Prepr 1997, 77, 149-150.

W15

"Degree of branching in hyperbranched polymers. Enhancement of the DB: Scope and Limitations"
H. Frey, D. Hölter, PMSE Prepr. 1997, 77, 226-227.

W14

"Hyperbranched polyallylsilanes bearing oxazoline groups as versatile building blocks for new polymer architectures"
C. Lach, H. Frey, R. Mülhaupt, PMSE Prepr. 1997, 77, 224.

W13

"Hyperbranched polyesters and polyurethanes prepared via the core-dilution method"
A. Burgath, R. Hanselmann, D. Hölter, H. Frey, PMSE Prepr. 1997, 77, 166.

W12

"Liquid crystal functionalized carbosilane dendrimers - molecules in the conflict between spherical shape and mesogen order"
K. Lorenz, D. Hölter, H. Frey, B. Stühn, PMSE Prepr. 1997, 77, 168.

W11

H. Frey, Chem. Unserer Zeit 1997, 31, 168.

W10

„Trends in der Polymerchemie 1996”
H. Frey, J. Kressler, W. Richtering, R. Mülhaupt, Nachrichten aus der Chemie 1997, 45, 198.

W9

"Polymer superlattices. Stick-ball molecules. Self-organizing mushrooms and films with two sides"
H. Frey, Chem. Unserer Zeit 1997, 31, 168.

W8

"Branched LC-bismethacrylates"
D. Hölter, H. Frey, R. Mülhaupt, Polym. Prepr. 1996, 37(1), 756.

W7

"Mesogen-functionalized carbosilane dendrimers - dendritic liquid crystalline polymers"
H. Frey, K. Lorenz, D. Hölter, R. Mülhaupt, Polym. Prepr. 1996, 37(1), 758.

W6

"Elektrochemie der Elektronenleiter"
T. Zerfaß, R. Mülhaupt, H. Frey, L. Matejcek, R. Nolte, A. Heinzel, K. Ledjeff-Hey Beiträge der Jahrestagung der GDCh-Fachgruppe Angewandte Elektrochemie vom 27. bis 29. September 1995 in Duisburg, Beck, F. (Ed.), GDCh-Monographie, 1996, 3, 190.

W5

"Trends in polymer chemistry 1995"
H. Frey, J. Kressler, W. Richtering, R. Mülhaupt, Acta Polym. 1996, 47, 131.

W4

"Polymerchemie 1995"
H. Frey, J. Kressler, W. Richtering, R. Mülhaupt, Nachrichten aus der Chemie 1996, 44, 203.

W3

"LC-dendrimers based on carbosilanarborols"
H. Frey, R. Mülhaupt, K. Lorenz, U. Rapp, F. J. Mayer-Posner, PMSE Prepr. 1995, 73, 127.

W2

"FT-IR-Studies on the mechanical response of the crystalline fraction in ultrastrong polyethylene tapes"
M. Möller, H. Frey, S. Sheiko, Symp. Proc. 3rd Dresden Polymer Discussion 1991, 132.

W1

"Solid-state transitions of poly[(di-n-hexyl/di-n-pentyl)silylene] copolymers"
H. Frey, K. Matyjaszewski, M. Moeller, D. Oelfin, Polymer Prepr. 1990, 31, 280.

To top of page

 

IV. Book Chapters

B6

Edited book: "Hyperbranched Polymers: Syntheses, Properties and Applications"
D. Yan, C. Gao, H. Frey Eds.; 2011, J. Wiley Publishers, New York and London

Links: [Wiley] [Amazon]

B5

Chapter 14 ”Hyperbranched polycarbosilanes and polycarbosiloxanes via hydrosilylation polymerization"€
H. Schüle, H. Frey, in Silicon Containing Dendritic Polymers, P. R. Dvornic, M. J. Owen, Eds., Springer, New York, 2009.

B4

"Polymorphism and molecular mobility of poly(silane)s and poly(silylenemethylene)s"
C. Müller, C. Schmidt, F. Koopmann, H. Frey, Organosilicon Chemistry IV: From Molecules to Materials, 2000, 558.

B3

"Enzyme-Catalyzed Synthesis of Hyperbranched Aliphatic Polyesters"
I. T. Neuner, M. Ursu, H. Frey, in Polymer Biocatalysis and Biomaterials, H. N. Cheng and R. A. Gross (Eds.), ACS Symp. Ser., Oxford University Press, 2005.

B2

"Sulfonated and Carboxylated Copoly(arylenesulfone)s for Fuel Cell Applications"
D. Poppe, T. Zerfass, R. Mülhaupt, H. Frey, in Functional Condensation Polymers, Kluwer Academic, New York, 2002, p. 83-94.

B1

"Molekulare Bäume im Trend: Dendrimere"
in Die Babywindel und 34 andere Chemiegeschichten, H. Frey, Ed. H-J. Quadbeck-Seeger and A. Fischer, Wiley-VCH, 2000, pp. 133.

 

V. Patents filed

To top of page

P36.

US2016272807
M. Haubs, K. Kurz, M. Bannwarth, K. Landfester, F. Wurm, H. Frey, R. Klein, Polyoxymethylene Nanoparticles 2016, .

P35.

SI2219676
P. Langguth, S. Grube, H. Frey, B. Obermeier, Quarternization of the Additive Amino Alkyl Methacrylate Copolymer E for Improving Permeability and Solubility of Pharmaceuticals 2016, .

P34.

US2015247006
R. Klein, C. Schüll, M. Haubs, K. Klaus, H. Frey, Block Copolymers Based on Linear Poly(oxymethylene)(POM) and Hyperbranched Poly(glycerol): Combining Polyacetals with Polyethers 2015, .

P33.

DE102013015112
H. Frey, H. Köhring, J. Saloga, Spaltbare Polyethylenglykol-(PEG)-Makromoleküle zum Einschluss von (Glyko-) Proteinen/Antigenen/Allergenen in abbaubaren Polyethylenglykol-(PEG)-Nanopartikeln sowie Verfahren zu ihrer Herstellung 2015, .

P32.

US2013123530
P. Böhm, H. Frey, T. Menke, Hydrophilic Polyorganosiloxanes 2013, .

P31.

US2012294813
H. Frey, D. Wilms, F. Wurm, Functional branched polyether copolymers and method for the production thereof 2012, .

P30.

DE102010021388
H. Frey, C. Tonhauser, D. Wilms, F. Wurm, M. Maskos, Kontinuierliches Verfahren zur Herstellung quantitativ endfunktionalisierter Polymere unter der Verwendung von Oxiranderivaten als Terminierungsreagenzien 2011, .

P29.

AT452157
J. Loccufier, L. Vanmaele, R. Claes, J. Van Luppen, Y. Chen, H. Frey, Strahlungshärtbare Zusammensetzungen 2010, .

P28.

DE 10 2010 028182
P. Böhm, H. Frey, T. Menke, Hydrophile Polyorganosiloxane 2010, .

P27.

DE 10 2009 059 104.4
H. Frey, D. Wilms, F. Wurm, Funktionelle verzweigte Polyether Copolymere sowie Verfahren zu ihrer Herstellung 2009, .

P26.

DE 200810160518
W. Arlt, M. Seiler, G. Sadowski, H. Frey, H. Kautz, R. Mühlhaupt, Hyperverzweigte Polymere als selektive Lösungsmittel für die Trennung engsiedender oder azeotroper Gemische 2008, .

P25.

US2008237907
J. E. Klee, U. Walz, A. Facher, C. Weber, R. Mülhaupt, H. Frey, M. Ekkehardt, Process for the preparation of a polymerizable dental composition 2008, .

P24.

EP 10 2007 060 175.3
S. Grube, B. Obermeier, H. Frey, P. Langguth, Quartärnisierung des Zusatz-stoffes Aminoalkyl Methacrylat Copolymer E zur Verbesserung der Permeabilität und Löslichkeit von Arzneistoffen 2007, .

P23.

US2006014853
L. Vanmaele, J. Loccufier, Y. Chen, H. Frey, Noval photoreactive polymer 2006, .

P22.

US2006014850
L. Vanmaele, J. Loccufier, Y. Chen, H. Frey, New polymeric initiator 2006, .

P21.

JP2006028518
L. Vanmaele, J. Loccufier, Y. Chen, H. Frey, Noval photoreactive polymer 2006, .

P20.

JP2006028514
L. Vanmaele, J. Loccufier, Y. Chen, H. Frey, New polymeric initiator 2006, .

P19.

JP2006028508
L. Vanmaele, J. Loccufier, Y. Chen, H. Frey, New polymeric co-initiator 2006, .

P18.

EP1674499
J. Loccufier, L. Vanmaele, R. Claes, J. Van Luppen, Y. Chen, H. Frey, Radiation curable compositions 2006, .

P17.

EP1616921
J. Loccufier, L. Vanmaele, J. Van Luppen, R. Claes, Y. Chen, H. Frey, Novel radiation curable compositions 2006, .

P16.

EP1616899
L. Vanmaele, J. Loccufier, Y. Chen, H. Frey, Novel photoreactive polymers 2006, .

P15.

EP1616897
L. Vanmaele, J. Loccufier, Y. Chen, H. Frey, Novel polymeric co-initiators 2006, .

P14.

US2004167296
J. E. Klee, U. Walz, J. Fiedler, R. Mülhaupt, H. Frey, M. Ekkehardt, Siloxane containing macromonomers and dental composites thereof 2004, .

P13.

US2004131995
J. E. Klee, U. Walz, A. Facher, C. Weber, R. Mülhaupt, H. Frey, M. Ekkehardt, Process for the preparation of a polymerizable dental composition 2004, .

P12.

AU2004212545
A. Burgath, U. Walz, D. Holter, J. Klee, R. Mühlaupt, H. Frey, Low shrinking ploymerizable dental material 2004, .

P11.

US2003055167
J. E. Klee, U. Walz, J. Fiedler, R. Mülhaupt, H. Frey, M. Ekkehardt, Siloxane containing macromonomers and dental composites thereof 2003, .

P10.

DE10160518
W. Arlt, M. Seiler, G. Sadowski, H. Frey, H. Kautz, R. Mülhaupt, Hyperbranched polymers as selective solvents for the separation of azeotropic mixtures or mixtures having very similar boiling points 2003, .

P9.

DE10101537 (2002),
J. E. Klee, U. Walz, A. Facher, C. Weber, R. Mülhaupt, H. Frey, E. Müh, Production of polymerizable dental compositions 2002, .

P8.

WO2001008639
J. E. Klee, U. Walz, J. Fiedler, R. Mülhaupt, H. Frey, E. Müh, Siloxane-containing macromonomers and dental composites thereof 2001, .

P7.

US5998499
J. E. Klee, H. Frey, D. Hölter, R. Mülhaupt, Liquid crystalline (meth)acrylate compounds, composition and method 1999, .

P6.

EP085207
R. Mülhaupt, T. Zerfass, H. Frey, K. Ledjeff-Hey, R. Nolte, Functionalized Copoly(m-Phenylene)-based solid polymer electrolytes 1998, .

P5.

WO9836729
J. E. Klee, U. Walz, D. Hölter, A. Burgath, H. Frey, R. Mülhaupt, Low shrinking polymerizable dental material 1998, .

P4.

DE19653484 (1998),
K. Ledjeff-Hey, R. Nolte, T. Zerfass, H. Frey, R. Mülhaupt, Preparation of membrane-electrode units for polymer electrolyte fuel cells 1998, .

P3.

WO9714674
J. E. Klee, H. Frey, D. Hölter, R. Mülhaupt, Liquid crystalline acrylates or a-substituted acrylates, curable dental compositions containing these compounds, and methods for using these compositions 1997, .

P2.

DE19535086
R. Mülhaupt, H. Frey, T. Zerfass, K. Ledjeff-Hey, R. Nolte, Preparation of functionalized copoly-m-phenylenes as solid electrolytes 1997, .

P1.

DE19516200
H. Frey, K. Lorenz, R. Mülhaupt, Carbosilane dendrimers with liquid-crystalline properties and their preparation and use 1996, .